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Ch.14 - Chemical Kinetics

Chapter 14, Problem 75c

(c) Do catalysts affect the overall enthalpy change for a reaction, the activation energy, or both?

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Hello everyone. Today we have the following problem. True or false. The overall entropy change and activation of activation energy of reaction are both affected by the catalyst. Well, let's start by defining what these are. So first let's define what a catalyst is. In simplest terms, a catalyst is a material that speeds up a chemical reaction. So it speeds up a chemical reaction and it doesn't undergo any sort of transformation itself. And so let's now look at what entropy changes. So entropy changes essentially just the total change and entropy for reaction of a reaction. And so since it solely depends on the chemical composition of the reaction of the reactions and products, it is not affected. So it is not affected by a catalyst because it only depends on the reactant and products don't reactant and the products. So let's now look at activation energy. So activation energy and simplest terms can be defined as the energy that's needed to basically Kickstarter reaction. So it's the minimum energy needed to start a reaction, basically turned a reactant into a product. And so the catalyst and how this is how it speeds up the reaction. It actually lowers so a catalyst lowers this energy. And so with that, this statement is going to be overall false because while the activation energy can be affected, the infinity change cannot. And with that, we've answered the question overall, I hope this helped. And until next time.
Related Practice
Textbook Question

The reaction 2 NO1g2 + Cl21g2¡2 NOCl1g2 was performed and the following data were obtained under conditions of constant 3Cl24:

(a) Is the following mechanism consistent with the data? NO1g2 + Cl21g2ΔNOCl21g2 1fast2 NOCl21g2 + NO1g2¡2 NOCl1g2 1slow2

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Textbook Question

You have studied the gas-phase oxidation of HBr by O2: 4 HBr(g) + O2(g) → 2 H2O(g) + 2 Br2(g)

You find the reaction to be first order with respect to HBr and first order with respect to O2. You propose the following mechanism:

HBr(g) + O2(g) → HOOBr(g)

HOOBr(g) + HBr(g) → 2 HOBr(g)

HOBr(g) + HBr(g) → H2O(g) + Br2(g)

(a) Confirm that the elementary reactions add to give the overall reaction.

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Textbook Question

You have studied the gas-phase oxidation of HBr by O2: 4 HBr(g) + O2(g) → 2 H2O(g) + 2 Br2(g)

You find the reaction to be first order with respect to HBr and first order with respect to O2. You propose the following mechanism:

HBr(g) + O2(g) → HOOBr(g)

HOOBr(g) + HBr(g) → 2 HOBr(g)

HOBr(g) + HBr(g) → H2O(g) + Br2(g)

(b) Based on the experimentally determined rate law, which step is rate determining?

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Textbook Question

(a) Most commercial heterogeneous catalysts are extremely finely divided solid materials. Why is particle size important?

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Textbook Question

The addition of NO accelerates the decomposition of N2O, possibly by the following mechanism: NO1g2 + N2O1g2¡N21g2 + NO21g2 2 NO21g2¡2 NO1g2 + O21g2 (b) Is NO serving as a catalyst or an intermediate in this reaction?

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Textbook Question

Many metallic catalysts, particularly the precious-metal ones, are often deposited as very thin films on a substance of high surface area per unit mass, such as alumina 1Al2O32 or silica 1SiO22. (b) How does the surface area affect the rate of reaction?

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