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Ch.13 - Properties of Solutions
Chapter 13, Problem 106a

Fluorocarbons (compounds that contain both carbon and fluorine) were, until recently, used as refrigerants. The compounds listed in the following table are all gases at 25 °C, and their solubilities in water at 25 °C and 1 atm fluorocarbon pressure are given as mass percentages. (a) For each fluorocarbon, calculate the molality of a saturated solution.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molality

Molality is a measure of the concentration of a solute in a solution, defined as the number of moles of solute per kilogram of solvent. It is particularly useful in situations where temperature changes may affect the volume of the solution, as it is based on mass rather than volume. To calculate molality, one must know the mass of the solute and the mass of the solvent, allowing for accurate concentration measurements in various chemical contexts.
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Saturated Solution

A saturated solution is one in which the maximum amount of solute has been dissolved in a solvent at a given temperature and pressure. Beyond this point, any additional solute will not dissolve and will remain as a solid. Understanding saturation is crucial for calculating molality, as it determines the amount of solute present in the solution, which is necessary for further concentration calculations.
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Solubility

Solubility refers to the ability of a substance (solute) to dissolve in a solvent at a specific temperature and pressure, often expressed in terms of mass percentage or molarity. In the context of fluorocarbons, solubility indicates how much of the gas can be dissolved in water, which is essential for determining the concentration of the solution. This property is influenced by factors such as temperature, pressure, and the nature of the solute and solvent.
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Related Practice
Textbook Question

Two beakers are placed in a sealed box at 25 °C. One beaker contains 30.0 mL of a 0.050 M aqueous solution of a nonvolatile nonelectrolyte. The other beaker contains 30.0 mL of a 0.035 M aqueous solution of NaCl. The water vapor from the two solutions reaches equilibrium. (a) In which beaker does the solution level rise, and in which one does it fall?

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Textbook Question

Two beakers are placed in a sealed box at 25 °C. One beaker contains 30.0 mL of a 0.050 M aqueous solution of a nonvolatile nonelectrolyte. The other beaker contains 30.0 mL of a 0.035 M aqueous solution of NaCl. The water vapor from the two solutions reaches equilibrium. (b) What are the volumes in the two beakers when equilibrium is attained, assuming ideal behavior?

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Textbook Question

Carbon disulfide (CS2) boils at 46.30 °C and has a density of 1.261 g/mL. (a) When 0.250 mol of a nondissociating solute is dissolved in 400.0 mL of CS2, the solution boils at 47.46 °C. What is the molal boiling-point-elevation constant for CS2?

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Textbook Question

Fluorocarbons (compounds that contain both carbon and fluorine) were, until recently, used as refrigerants. The compounds listed in the following table are all gases at 25 °C, and their solubilities in water at 25 °C and 1 atm fluorocarbon pressure are given as mass percentages. (c) Infants born with severe respiratory problems are sometimes given liquid ventilation: They breathe a liquid that can dissolve more oxygen than air can hold. One of these liquids is a fluorinated compound, CF3(CF2)7Br. The solubility of oxygen in this liquid is 66 mL O2 per 100 mL liquid. In contrast, air is 21% oxygen by volume. Calculate the moles of O2 present in an infant’s lungs (volume: 15 mL) if the infant takes a full breath of air compared to taking a full “breath” of a saturated solution of O2 in the fluorinated liquid. Assume a pressure of 1 atm in the lungs.

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Textbook Question

At ordinary body temperature (37 °C), the solubility of N2 in water at ordinary atmospheric pressure (1.0 atm) is 0.015 g/L. Air is approximately 78 mol % N2. (b) At a depth of 100 ft in water, the external pressure is 4.0 atm. What is the solubility of N2 from air in blood at this pressure?

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Textbook Question
A series of anions is shown below:

The anion on the far right is called 'BARF' by chemists, as its common abbreviation sounds similar to this word. (d) Tetrabutylammonium, (CH3CH2CH2CH2)4N + is a bulky cation. Which anion, when paired with the tetrabutylammonium cation, would lead to a salt that will be most soluble in nonpolar solvents?
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