Chapter 13, Problem 107b
At ordinary body temperature (37 °C), the solubility of N2 in water at ordinary atmospheric pressure (1.0 atm) is 0.015 g/L. Air is approximately 78 mol % N2. (b) At a depth of 100 ft in water, the external pressure is 4.0 atm. What is the solubility of N2 from air in blood at this pressure?
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Carbon disulfide (CS2) boils at 46.30 °C and has a density of 1.261 g/mL. (a) When 0.250 mol of a nondissociating solute is dissolved in 400.0 mL of CS2, the solution boils at 47.46 °C. What is the molal boiling-point-elevation constant for CS2?
Fluorocarbons (compounds that contain both carbon and fluorine) were, until recently, used as refrigerants. The compounds listed in the following table are all gases at 25 °C, and their solubilities in water at 25 °C and 1 atm fluorocarbon pressure are given as mass percentages. (a) For each fluorocarbon, calculate the molality of a saturated solution.
Fluorocarbons (compounds that contain both carbon and fluorine) were, until recently, used as refrigerants. The compounds listed in the following table are all gases at 25 °C, and their solubilities in water at 25 °C and 1 atm fluorocarbon pressure are given as mass percentages. (c) Infants born with severe respiratory problems are sometimes given liquid ventilation: They breathe a liquid that can dissolve more oxygen than air can hold. One of these liquids is a fluorinated compound, CF3(CF2)7Br. The solubility of oxygen in this liquid is 66 mL O2 per 100 mL liquid. In contrast, air is 21% oxygen by volume. Calculate the moles of O2 present in an infant’s lungs (volume: 15 mL) if the infant takes a full breath of air compared to taking a full “breath” of a saturated solution of O2 in the fluorinated liquid. Assume a pressure of 1 atm in the lungs.
A series of anions is shown below:
The anion on the far right is called 'BARF' by chemists, as its common abbreviation sounds similar to this word. (a) What is the central atom and the number of electronpair domains around the central atom in each of these anions?
A series of anions is shown below:
The anion on the far right is called 'BARF' by chemists, as its common abbreviation sounds similar to this word. (b) What is the electron-domain geometry around the central B in BARF?