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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 101

Which statement correctly describes a difference between graphene and graphite? (a) Graphene is a molecule but graphite is not. (b) Graphene is a single sheet of carbon atoms and graphite contains many, and larger, sheets of carbon atoms. (c) Graphene is an insulator but graphite is a metal. (d) Graphite is pure carbon but graphene is not. (e) The carbons are sp2 hybridized in graphene but sp3 hybridized in graphite.

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1
Understand the structure of graphene: Graphene is a single layer of carbon atoms arranged in a two-dimensional honeycomb lattice.
Understand the structure of graphite: Graphite consists of many layers of graphene stacked on top of each other, with weak van der Waals forces between the layers.
Compare the structures: Graphene is a single sheet, while graphite is composed of multiple sheets of graphene.
Consider the hybridization: Both graphene and graphite have carbon atoms that are sp2 hybridized, not sp3.
Evaluate the options: Option (b) correctly describes the difference between graphene and graphite, as graphene is a single sheet and graphite contains many sheets.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Structure of Graphene and Graphite

Graphene is a single layer of carbon atoms arranged in a two-dimensional honeycomb lattice, while graphite consists of multiple layers of graphene stacked together. This structural difference leads to distinct physical properties, such as electrical conductivity and mechanical strength, making graphene a highly sought-after material in various applications.
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Hybridization of Carbon Atoms

In graphene, each carbon atom is sp2 hybridized, meaning it forms three sigma bonds with neighboring carbon atoms and has one unhybridized p orbital that contributes to delocalized pi bonding. In contrast, graphite's carbon atoms are also primarily sp2 hybridized, allowing for similar bonding characteristics, but the presence of multiple layers affects the overall properties of the material.
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Electrical Conductivity

Graphene is an excellent conductor of electricity due to its structure, which allows for the free movement of electrons across its surface. Graphite, while also a good conductor, exhibits different conductivity characteristics because of its layered structure, which can impede electron flow between layers. Understanding these differences is crucial for applications in electronics and materials science.
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Related Practice
Textbook Question

CdS has a band gap of 2.4 eV. If large crystals of CdS are illuminated with ultraviolet light, they emit light equal to the band gap energy. (c) What about red light?

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Open Question
Indicate whether each statement is true or false: (a) The band gap of a semiconductor decreases as the particle size decreases in the 1–10-nm range. (b) The light that is emitted from a semiconductor, upon external stimulation, becomes longer in wavelength as the particle size of the semiconductor decreases.
Open Question
Indicate whether this statement is true or false: If you want a semiconductor that emits blue light, you could either use a material that has a band gap corresponding to the energy of a blue photon or you could use a material that has a smaller band gap but make an appropriately sized nanoparticle of the same material.
Open Question
What evidence supports the notion that buckyballs are actual molecules and not extended materials? (a) Buckyballs are made of carbon. (b) Buckyballs have a well-defined atomic structure and molecular weight. (c) Buckyballs have a well-defined melting point. (d) Buckyballs are semiconductors. (e) More than one of the previous choices.
Textbook Question

Selected chlorides have the following melting points: NaCl (801 °C), MgCl2 (714 °C), PCl3 (-94 °C), SCl2 (-121 °C) (a) For each compound, indicate what type its solid form is (molecular, metallic, ionic, or covalent-network).

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Open Question
A face-centered tetragonal lattice is not one of the 14 three-dimensional lattices. Show that a face-centered tetragonal unit cell can be redefined as a body-centered tetragonal lattice with a smaller unit cell.