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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 113b

Silicon carbide, SiC, has the three-dimensional structure shown in the figure.
3D structure of silicon carbide (SiC) showing atomic arrangement for bonding analysis.
(b) Would you expect the bonding in SiC to be predominantly ionic, metallic, or covalent?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Bonding Types

There are three primary types of chemical bonding: ionic, covalent, and metallic. Ionic bonds form between atoms with significantly different electronegativities, resulting in the transfer of electrons. Covalent bonds involve the sharing of electrons between atoms with similar electronegativities, while metallic bonds occur in metals where electrons are delocalized, allowing for conductivity and malleability.
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Electronegativity

Electronegativity is a measure of an atom's ability to attract and hold onto electrons. In the context of bonding, the difference in electronegativity between two atoms can help predict the type of bond that will form. A large difference typically indicates ionic bonding, while a small difference suggests covalent bonding. Silicon (Si) and carbon (C) have similar electronegativities, which influences the nature of their bonding in silicon carbide.
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Crystal Structure

The crystal structure of a material describes the orderly arrangement of atoms within it. In silicon carbide (SiC), the three-dimensional structure shown in the image indicates a covalent network, where each silicon atom is covalently bonded to carbon atoms in a tetrahedral arrangement. This structure contributes to the material's hardness and thermal stability, characteristics typical of covalent compounds.
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Related Practice
Textbook Question
Introduction of carbon into a metallic lattice generally results in a harder, less ductile substance with lower electrical and thermal conductivities. Explain why this might be so.
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Textbook Question
For each of the intermetallic compounds shown in Figure 12.17 determine the number of each type of atom in the unit cell. Do your answers correspond to the ratios expected from the empirical formulas: Ni3Al?

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Textbook Question

What type of lattice—primitive cubic, body-centered cubic, or face-centered cubic—does each of the following structure types possess: (e) ZnS?

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Textbook Question

Energy bands are considered continuous due to the large number of closely spaced energy levels. The range of energy levels in a crystal of copper is approximately 1 * 10–19 J. Assuming equal spacing between levels, the spacing between energy levels may be approximated by dividing the range of energies by the number of atoms in the crystal. (b) Determine the average spacing in J between energy levels in the copper metal in part (a).

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Textbook Question

Sodium oxide (Na2O) adopts a cubic structure with Na atoms represented by green spheres and O atoms by red spheres.

(c) The unit cell edge length is 5.550 Å. Determine the density of Na2O.

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Textbook Question

In their study of X-ray diffraction, William and Lawrence Bragg determined that the relationship among the wavelength of the radiation 1l2, the angle at which the radiation is diffracted 1u2, and the distance between planes of atoms in the crystal that cause the diffraction (d) is given by nl = 2d sin u. X rays from a copper X-ray tube that have a wavelength of 1.54 Å are diffracted at an angle of 14.22 degrees by crystalline silicon. Using the Bragg equation, calculate the distance between the planes of atoms responsible for diffraction in this crystal, assuming n = 1 (first-order diffraction).

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