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Ch.10 - Gases
Chapter 10, Problem 74a

A sample of 3.00 g of SO21g2 originally in a 5.00-L vessel at 21 °C is transferred to a 10.0-L vessel at 26 °C. A sample of 2.35 g of N21g2 originally in a 2.50-L vessel at 20 °C is transferred to this same 10.0-L vessel. (a) What is the partial pressure of SO21g2 in the larger container?

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1
Calculate the number of moles of SO_2 using its mass and molar mass.
Use the ideal gas law, PV = nRT, to find the initial pressure of SO_2 in the 5.00-L vessel.
Determine the new temperature in Kelvin for the 10.0-L vessel.
Apply the ideal gas law again to find the partial pressure of SO_2 in the 10.0-L vessel, using the moles calculated and the new volume and temperature.
Ensure the units are consistent throughout the calculations, especially for R, the ideal gas constant.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law is essential for calculating the behavior of gases under varying conditions, allowing us to determine the partial pressure of a gas when its amount and the conditions of the system are known.
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Partial Pressure

Partial pressure is the pressure exerted by a single component of a gas mixture. According to Dalton's Law of Partial Pressures, the total pressure of a gas mixture is the sum of the partial pressures of each individual gas. Understanding this concept is crucial for calculating the contribution of SO2 to the total pressure in the larger vessel.
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Molar Mass and Mass to Moles Conversion

To find the number of moles of a gas from its mass, the molar mass of the gas is used in the conversion formula: moles = mass (g) / molar mass (g/mol). For SO2, knowing its molar mass (approximately 64.07 g/mol) allows us to convert the given mass into moles, which is necessary for applying the Ideal Gas Law.
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Related Practice
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A rigid vessel containing a 3:1 mol ratio of carbon dioxide and water vapor is held at 200 °C where it has a total pressure of 202.7 kPa. If the vessel is cooled to 10 °C so that all of the water vapor condenses, what is the pressure of carbon dioxide? Neglect the volume of the liquid water that forms on cooling.
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A quantity of N2 gas originally held at 531.96 kPa pressure in a 1.00-L container at 26 °C is transferred to a 12.5-L container at 20 °C. A quantity of O2 gas originally at 531.96 kPa and 26 °C in a 5.00-L container is transferred to this same container. What is the total pressure in the new container?
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