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Ch.10 - Gases
Chapter 10, Problem 63

A mixture containing 0.50 mol H2(g), 1.00 mol O2(g), and 3.50 mol N2(g) is confined in a 25.0-L vessel at 25 °C. Calculate the partial pressure of H2, O2, and N2.

Verified step by step guidance
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Step 1: Use the ideal gas law to find the total pressure of the gas mixture. The ideal gas law is given by the equation: \( PV = nRT \), where \( P \) is the pressure, \( V \) is the volume, \( n \) is the number of moles, \( R \) is the ideal gas constant (0.0821 L·atm/mol·K), and \( T \) is the temperature in Kelvin. First, convert the temperature from Celsius to Kelvin by adding 273.15 to the Celsius temperature.
Step 2: Calculate the total number of moles in the mixture by adding the moles of each gas: \( n_{\text{total}} = n_{\text{H}_2} + n_{\text{O}_2} + n_{\text{N}_2} \).
Step 3: Substitute the total number of moles, the volume of the vessel, the temperature in Kelvin, and the ideal gas constant into the ideal gas law equation to solve for the total pressure \( P_{\text{total}} \).
Step 4: Use Dalton's Law of Partial Pressures to find the partial pressure of each gas. According to Dalton's Law, the partial pressure of a gas in a mixture is equal to the mole fraction of that gas multiplied by the total pressure. Calculate the mole fraction of each gas: \( \text{Mole fraction of } H_2 = \frac{n_{\text{H}_2}}{n_{\text{total}}} \), \( \text{Mole fraction of } O_2 = \frac{n_{\text{O}_2}}{n_{\text{total}}} \), \( \text{Mole fraction of } N_2 = \frac{n_{\text{N}_2}}{n_{\text{total}}} \).
Step 5: Calculate the partial pressure of each gas by multiplying its mole fraction by the total pressure: \( P_{\text{H}_2} = \text{Mole fraction of } H_2 \times P_{\text{total}} \), \( P_{\text{O}_2} = \text{Mole fraction of } O_2 \times P_{\text{total}} \), \( P_{\text{N}_2} = \text{Mole fraction of } N_2 \times P_{\text{total}} \).
Related Practice
Textbook Question
During a person's typical breathing cycle, the CO2 concentration in the expired air rises to a peak of 4.6% by volume. (a) Calculate the partial pressure of the CO2 in the expired air at its peak, assuming 1 atm pressure and a body temperature of 37 °C.
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Textbook Question
Acetylene gas, C2H21g2, can be prepared by the reaction of calcium carbide with water: CaC21s2 + 2 H2O1l2¡Ca1OH221aq2 + C2H21g2 Calculate the volume of C2H2 that is collected over water at 23 °C by reaction of 1.524 g of CaC2 if the total pressure of the gas is 100.4 kPa. (The vapor pressure of water is tabulated in Appendix B.)
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Textbook Question

Consider a mixture of two gases, A and B, confined in a closed vessel. A quantity of a third gas, C, is added to the same vessel at the same temperature. How does the addition of gas C affect the following: (a) the partial pressure of gas A?

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Open Question
A deep-sea diver uses a gas cylinder with a volume of 10.0 L and a content of 51.2 g of O2 and 32.6 g of He. Calculate the partial pressure of each gas and the total pressure if the temperature of the gas is 19 °C.
Textbook Question

The atmospheric concentration of CO2 gas is presently 407 ppm (parts per million, by volume; that is, 407 L of every 106 L of the atmosphere are CO2). What is the mole fraction of CO2 in the atmosphere?.

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Textbook Question
A plasma-screen TV contains thousands of tiny cells filled with a mixture of Xe, Ne, and He gases that emits light of specific wavelengths when a voltage is applied. A particular plasma cell, 0.900 mm * 0.300 mm * 10.0 mm, contains 4% Xe in a 1:1 Ne:He mixture at a total pressure of 66.66 kPa. Calculate the number of Ne atoms in the cell and state the assumptions you need to make in your calculation.
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