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Ch.4 - Chemical Quantities & Aqueous Reactions
Chapter 4, Problem 92b,c,d

Complete and balance each gas-evolution equation. b. HCl(aq) + KHCO3(aq) → c. HC2H3O2(aq) + NaHSO3(aq) → d. (NH4)2SO4(aq) + Ca(OH)2(aq) →

Verified step by step guidance
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Step 1: Identify the reactants and products for each reaction. For reaction b, the reactants are HCl(aq) and KHCO_3(aq). For reaction c, the reactants are HC_2H_3O_2(aq) and NaHSO_3(aq). For reaction d, the reactants are (NH_4)_2SO_4(aq) and Ca(OH)_2(aq).
Step 2: Determine the gas that evolves in each reaction. In reaction b, the reaction between an acid and a bicarbonate typically produces carbon dioxide gas (CO_2). In reaction c, the reaction between an acid and a bisulfite typically produces sulfur dioxide gas (SO_2). In reaction d, the reaction between ammonium sulfate and calcium hydroxide typically produces ammonia gas (NH_3).
Step 3: Write the unbalanced chemical equations including the evolved gases. For reaction b: HCl(aq) + KHCO_3(aq) → KCl(aq) + H_2O(l) + CO_2(g). For reaction c: HC_2H_3O_2(aq) + NaHSO_3(aq) → NaC_2H_3O_2(aq) + H_2O(l) + SO_2(g). For reaction d: (NH_4)_2SO_4(aq) + Ca(OH)_2(aq) → CaSO_4(s) + H_2O(l) + NH_3(g).
Step 4: Balance each chemical equation by ensuring the same number of each type of atom on both sides of the equation. Start by balancing the atoms that appear in the least number of compounds, and then balance the remaining atoms.
Step 5: Verify that each equation is balanced by counting the atoms of each element on both sides of the equation. Ensure that the charges are balanced if the reaction involves ionic species.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Gas-Evolution Reactions

Gas-evolution reactions are chemical reactions that produce a gas as one of the products. These reactions often involve the combination of an acid with a carbonate or bicarbonate, leading to the release of carbon dioxide. Understanding the nature of these reactions is crucial for predicting the products and balancing the equations correctly.
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Balancing Chemical Equations

Balancing chemical equations involves ensuring that the number of atoms of each element is the same on both sides of the equation. This is achieved by adjusting the coefficients of the reactants and products. Mastery of this concept is essential for accurately representing the conservation of mass in chemical reactions.
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Acid-Base Reactions

Acid-base reactions involve the transfer of protons (H⁺ ions) between reactants. In the context of the given question, acids like HCl and HC₂H₃O₂ react with bases such as KHCO₃ and Ca(OH)₂, leading to the formation of salts and water. Recognizing the roles of acids and bases is vital for predicting the products of these reactions.
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