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Ch.5 - Gases
Chapter 5, Problem 47

A wine-dispensing system uses argon canisters to pressurize and preserve wine in the bottle. An argon canister for the system has a volume of 55.0 mL and contains 26.0 g of argon. When the argon is released from the canister, it expands to fill the wine bottle. How many 750.0-mL wine bottles can be purged with the argon in the canister at a pressure of 1.20 atm and a temperature of 295 K? Assuming ideal gas behavior, what is the pressure in the canister at 295 K?

Verified step by step guidance
1
Calculate the number of moles of argon in the canister using the molar mass of argon (approximately 39.95 g/mol).
Use the ideal gas law equation \( PV = nRT \) to find the pressure in the canister. Here, \( P \) is the pressure, \( V \) is the volume of the canister, \( n \) is the number of moles calculated in the previous step, \( R \) is the ideal gas constant (0.0821 L·atm/mol·K), and \( T \) is the temperature in Kelvin.
Convert the volume of the canister from mL to L for consistency in units.
Calculate the total volume of argon gas at 1.20 atm and 295 K using the ideal gas law, rearranging it to solve for \( V \) (volume).
Determine how many 750.0-mL wine bottles can be filled by dividing the total volume of argon gas by the volume of one wine bottle (converted to liters).

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law allows us to predict the behavior of gases under various conditions and is essential for solving problems involving gas expansion and compression.
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Ideal Gas Law Formula

Molar Mass and Moles

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). To find the number of moles of a gas, you can use the formula n = mass/molar mass. In this question, knowing the mass of argon (26.0 g) and its molar mass (approximately 40.00 g/mol) is crucial for determining how many moles of argon are available to fill the wine bottles.
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Gas Expansion and Pressure Calculation

When a gas expands, it occupies a larger volume, which can affect its pressure and temperature. In this scenario, we need to calculate the pressure of the argon gas in the canister at a given temperature using the Ideal Gas Law. Additionally, understanding how to apply the law to find the number of wine bottles that can be purged involves calculating the final pressure and volume of the gas after expansion.
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Related Practice
Textbook Question

A weather balloon is inflated to a volume of 28.5 L at a pressure of 748 mmHg and a temperature of 28.0 °C. The balloon rises in the atmosphere to an altitude of approximately 25,000 ft, where the pressure is 385 mmHg and the temperature is -15.0 °C. Assuming the balloon can freely expand, calculate the volume of the balloon at this altitude.

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Textbook Question

A piece of dry ice (solid carbon dioxide) with a mass of 28.8 g sublimes (converts from solid to gas) into a large balloon. Assuming that all of the carbon dioxide ends up in the balloon, what is the volume of the balloon at 22 °C and a pressure of 742 mmHg?

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Textbook Question

A 1.0-L container of liquid nitrogen is kept in a closet measuring 1.0 m by 1.0 m by 2.0 m. Assuming that the container is completely full, that the temperature is 25.0 °C, and that the atmospheric pressure is 1.0 atm, calculate the percent (by volume) of air that is displaced if all of the liquid nitrogen evaporates. (Liquid nitrogen has a density of 0.807 g/mL.)

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Open Question
Cyclists sometimes use pressurized carbon dioxide inflators to inflate a bicycle tire in the event of a flat. These inflators use metal cartridges that contain 16.0 g of carbon dioxide. At 298 K, to what pressure (in psi) can the carbon dioxide in the cartridge inflate a 3.45-L mountain bike tire? (Note: Assume that atmospheric pressure is 14.7 psi; the gauge pressure is the total pressure minus the atmospheric pressure.)
Textbook Question

Which gas sample has the greatest pressure? Assume that all the samples are at the same temperature. Explain.

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Textbook Question

This picture represents a sample of gas at a pressure of 1 atm, a volume of 1 L, and a temperature of 25 °C. Draw a similar picture showing what would happen to the sample if the volume were reduced to 0.5 L and the temperature were increased to 250 °C. What would happen to the pressure?

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