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Ch.5 - Gases
Chapter 5, Problem 45

A piece of dry ice (solid carbon dioxide) with a mass of 28.8 g sublimes (converts from solid to gas) into a large balloon. Assuming that all of the carbon dioxide ends up in the balloon, what is the volume of the balloon at 22 °C and a pressure of 742 mmHg?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law allows us to calculate the volume of a gas when the other variables are known.
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Molar Mass of Carbon Dioxide

The molar mass of carbon dioxide (CO2) is essential for converting the mass of dry ice into moles. Carbon dioxide has a molar mass of approximately 44.01 g/mol, which is calculated by adding the atomic masses of one carbon atom (12.01 g/mol) and two oxygen atoms (16.00 g/mol each). Knowing the molar mass allows us to determine how many moles of CO2 are present in the 28.8 g of dry ice.
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Gas Behavior Under Different Conditions

Gases behave differently under varying conditions of temperature and pressure. According to the principles of gas behavior, an increase in temperature typically leads to an increase in volume if pressure is held constant, and vice versa. Understanding these relationships is crucial for predicting how the volume of gas will change under specific conditions, such as the 22 °C and 742 mmHg mentioned in the question.
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Related Practice
Textbook Question

What is the temperature of 0.52 mol of gas at a pressure of 1.3 atm and a volume of 11.8 L?

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Textbook Question

An automobile tire has a maximum rating of 38.0 psi (gauge pressure). The tire is inflated (while cold) to a volume of 11.8 L and a gauge pressure of 36.0 psi at a temperature of 12.0 °C. On a hot day, the tire warms to 65.0 °C, and its volume expands to 12.2 L. Does the pressure in the tire exceed its maximum rating? (Note: The gauge pressure is the difference between the total pressure and atmospheric pressure. In this case, assume that atmospheric pressure is 14.7 psi.)

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Textbook Question

A weather balloon is inflated to a volume of 28.5 L at a pressure of 748 mmHg and a temperature of 28.0 °C. The balloon rises in the atmosphere to an altitude of approximately 25,000 ft, where the pressure is 385 mmHg and the temperature is -15.0 °C. Assuming the balloon can freely expand, calculate the volume of the balloon at this altitude.

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Textbook Question

A 1.0-L container of liquid nitrogen is kept in a closet measuring 1.0 m by 1.0 m by 2.0 m. Assuming that the container is completely full, that the temperature is 25.0 °C, and that the atmospheric pressure is 1.0 atm, calculate the percent (by volume) of air that is displaced if all of the liquid nitrogen evaporates. (Liquid nitrogen has a density of 0.807 g/mL.)

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Open Question
A wine-dispensing system uses argon canisters to pressurize and preserve wine in the bottle. An argon canister for the system has a volume of 55.0 mL and contains 26.0 g of argon. When the argon is released from the canister, it expands to fill the wine bottle. How many 750.0-mL wine bottles can be purged with the argon in the canister at a pressure of 1.20 atm and a temperature of 295 K? Assuming ideal gas behavior, what is the pressure in the canister at 295 K?
Open Question
Cyclists sometimes use pressurized carbon dioxide inflators to inflate a bicycle tire in the event of a flat. These inflators use metal cartridges that contain 16.0 g of carbon dioxide. At 298 K, to what pressure (in psi) can the carbon dioxide in the cartridge inflate a 3.45-L mountain bike tire? (Note: Assume that atmospheric pressure is 14.7 psi; the gauge pressure is the total pressure minus the atmospheric pressure.)