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Ch.5 - Gases
Chapter 5, Problem 50

This picture represents a sample of gas at a pressure of 1 atm, a volume of 1 L, and a temperature of 25 °C. Draw a similar picture showing what would happen to the sample if the volume were reduced to 0.5 L and the temperature were increased to 250 °C. What would happen to the pressure?
Illustration of a gas sample in a flask at 1 atm, 1 L, and 25 °C, with pink particles representing gas molecules.

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Step 1: Identify the initial conditions of the gas sample: pressure (P1) = 1 atm, volume (V1) = 1 L, and temperature (T1) = 25 °C (which is 298 K).
Step 2: Convert the final temperature to Kelvin: T2 = 250 °C + 273 = 523 K.
Step 3: Use the combined gas law to relate the initial and final states of the gas: (P1 * V1) / T1 = (P2 * V2) / T2.
Step 4: Substitute the known values into the combined gas law equation: (1 atm * 1 L) / 298 K = (P2 * 0.5 L) / 523 K.
Step 5: Solve for the final pressure (P2) by isolating P2 in the equation.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure (P), volume (V), temperature (T), and number of moles (n) of a gas. It is expressed as PV = nRT, where R is the ideal gas constant. This law helps predict how changing one of these variables affects the others, making it essential for understanding gas behavior under different conditions.
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Charles's Law

Charles's Law states that the volume of a gas is directly proportional to its temperature when pressure is held constant. This means that if the temperature increases, the volume must also increase, and vice versa. In the context of the question, reducing the volume while increasing the temperature will significantly affect the pressure of the gas.
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Boyle's Law

Boyle's Law describes the inverse relationship between the pressure and volume of a gas at constant temperature. According to this law, if the volume of a gas decreases, the pressure increases, provided the temperature remains constant. This principle is crucial for understanding how the pressure of the gas sample will change when its volume is halved.
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Related Practice
Open Question
A wine-dispensing system uses argon canisters to pressurize and preserve wine in the bottle. An argon canister for the system has a volume of 55.0 mL and contains 26.0 g of argon. When the argon is released from the canister, it expands to fill the wine bottle. How many 750.0-mL wine bottles can be purged with the argon in the canister at a pressure of 1.20 atm and a temperature of 295 K? Assuming ideal gas behavior, what is the pressure in the canister at 295 K?
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