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Ch.13 - Solutions
Chapter 13, Problem 72

A solution contains naphthalene (C10H8) dissolved in hexane (C6H14) at a concentration of 12.35% naphthalene by mass. Calculate the vapor pressure of hexane above the solution at 25 °C. The vapor pressure of pure hexane at 25 °C is 151 torr.

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Determine the mass of naphthalene and hexane in the solution. Assume a total mass of 100 g for simplicity, which means 12.35 g of naphthalene and 87.65 g of hexane.
Calculate the number of moles of naphthalene (C_{10}H_{8}) using its molar mass (128.17 g/mol).
Calculate the number of moles of hexane (C_{6}H_{14}) using its molar mass (86.18 g/mol).
Find the mole fraction of hexane in the solution using the formula: \( \text{Mole fraction of hexane} = \frac{\text{moles of hexane}}{\text{moles of hexane} + \text{moles of naphthalene}} \).
Apply Raoult's Law to find the vapor pressure of hexane above the solution: \( P_{\text{solution}} = \chi_{\text{hexane}} \times P^0_{\text{hexane}} \), where \( P^0_{\text{hexane}} \) is the vapor pressure of pure hexane (151 torr).
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Textbook Question

Which solution has the highest vapor pressure? a. 20.0 g of glucose (C6H12O6) in 100.0 mL of water b. 20.0 g of sucrose (C12H22O11) in 100.0 mL of water c. 10.0 g of potassium acetate KC2H3O2 in 100.0 mL of water

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Textbook Question

Calculate the vapor pressure of a solution containing 24.5 g of glycerin (C3H8O3) in 135 mL of water at 30.0 °C. The vapor pressure of pure water at this temperature is 31.8 torr. Assume that glycerin is not volatile and dissolves molecularly (i.e., it is not ionic), and use a density of 1.00 g/mL for the water.

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Textbook Question

A solution contains 50.0 g of heptane (C7H16) and 50.0 g of octane (C8H18) at 25 °C. The vapor pressures of pure heptane and pure octane at 25 °C are 45.8 torr and 10.9 torr, respectively. Assuming ideal behavior, answer the following: d. Why is the composition of the vapor different from the composition of the solution?

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Textbook Question

A solution contains a mixture of pentane and hexane at room temperature. The solution has a vapor pressure of 258 torr. Pure pentane and hexane have vapor pressures of 425 torr and 151 torr, respectively, at room temperature. What is the mole fraction composition of the mixture? (Assume ideal behavior.)

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Open Question
A solution contains 4.08 g of chloroform (CHCl3) and 9.29 g of acetone (CH3COCH3). The vapor pressures at 35 °C of pure chloroform and pure acetone are 295 torr and 332 torr, respectively. Assuming ideal behavior, calculate the vapor pressures of each of the components and the total vapor pressure above the solution. The experimentally measured total vapor pressure of the solution at 35 °C is 312 torr. Is the solution ideal? If not, what can you say about the relative strength of chloroform–acetone interactions compared to the acetone–acetone and chloroform–chloroform interactions?