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Ch.1 - Matter, Measurement & Problem Solving
Chapter 1, Problem 133

Liquid nitrogen has a density of 0.808 g/mL and boils at 77 K. Researchers often purchase liquid nitrogen in insulated 175 L tanks. The liquid vaporizes quickly to gaseous nitrogen (which has a density of 1.15 g/L at room temperature and atmospheric pressure) when the liquid is removed from the tank. Suppose that all 175 L of liquid nitrogen in a tank accidentally vaporized in a lab that measured 10.00 m * 10.00 m * 2.50 m. What maximum fraction of the air in the room could be displaced by the gaseous nitrogen?

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1
Calculate the mass of liquid nitrogen using its density and volume: \( \text{mass} = \text{density} \times \text{volume} = 0.808 \, \text{g/mL} \times 175,000 \, \text{mL} \).
Convert the mass of liquid nitrogen to moles using the molar mass of nitrogen (N2), which is approximately 28.02 g/mol: \( \text{moles} = \frac{\text{mass}}{\text{molar mass}} \).
Determine the volume of gaseous nitrogen at room temperature and atmospheric pressure using the ideal gas law: \( PV = nRT \), where \( P \) is pressure, \( V \) is volume, \( n \) is moles, \( R \) is the ideal gas constant, and \( T \) is temperature in Kelvin.
Calculate the volume of the room: \( \text{volume} = 10.00 \, \text{m} \times 10.00 \, \text{m} \times 2.50 \, \text{m} \).
Determine the fraction of the room's air displaced by dividing the volume of gaseous nitrogen by the volume of the room.
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