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Ch.19 - Chemical Thermodynamics

Chapter 19, Problem 100c

The conversion of natural gas, which is mostly methane, into products that contain two or more carbon atoms, such as ethane (C2H6), is a very important industrial chemical process. In principle, methane can be converted into ethane and hydrogen: 2 CH4(g) → C2H6(g) + H2(g) In practice, this reaction is carried out in the presence of oxygen: 2 CH4(g) + 12 O2(g) → C2H6(g) + H2O(g) (c) Explain how the preceding reactions are an example of driving a nonspontaneous reaction, as discussed in the 'Chemistry and Life' box in Section 19.7.

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