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Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
Chapter 10, Problem 88a

The structure of acetylsalicylic acid (aspirin) is shown here. How many π bonds are present in acetylsalicylic acid?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

π Bonds

π bonds are a type of covalent bond that occurs when two lobes of one involved atomic orbital overlap with two lobes of another, forming a bond that is generally weaker than a sigma bond. They are typically found in double and triple bonds, where one bond is a sigma bond and the others are π bonds. Understanding the structure of molecules, including the presence of π bonds, is crucial for analyzing their chemical properties.
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Molecular Structure

The molecular structure of a compound refers to the arrangement of atoms within the molecule, including the types of bonds (single, double, triple) and the spatial orientation of these bonds. In the case of acetylsalicylic acid, recognizing how the atoms are connected and the presence of functional groups is essential for determining the number of π bonds. This structural understanding aids in predicting the reactivity and properties of the molecule.
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Molecular Formula

Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. In acetylsalicylic acid, the presence of carboxylic acid and ester functional groups influences its chemical behavior and interactions. Identifying these groups helps in understanding the overall structure and the number of π bonds present in the molecule.
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Related Practice
Open Question
For each compound, draw the Lewis structure, determine the geometry using VSEPR theory, determine whether the molecule is polar, identify the hybridization of all interior atoms, and make a sketch of the molecule according to valence bond theory showing orbital overlap: a. COF2 (carbon is the central atom) b. S2Cl2 (ClSSCl) c. SF4.
Open Question
For each compound, draw the Lewis structure, determine the geometry using VSEPR theory, determine whether the molecule is polar, identify the hybridization of all interior atoms, and make a sketch of the molecule according to valence bond theory, showing orbital overlap. a. IF5 b. CH2CHCH3 c. CH3SH
Textbook Question

The genetic code is based on four different bases with the structures shown here. Assign a geometry and hybridization to each interior atom in these four bases. d. guanine

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Textbook Question

The structure of acetylsalicylic acid (aspirin) is shown here. How many sigma bonds?

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Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (a) vitamin C

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Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (c) niacin (vitamin B3)

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