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Ch.13 - Solutions
Chapter 13, Problem 107

An aqueous solution contains 12.5% NaCl by mass. What mass of water (in grams) is contained in 2.5 L of the vapor above this solution at 55 °C? The vapor pressure of pure water at 55 °C is 118 torr. (Assume complete dissociation of NaCl.)

Verified step by step guidance
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<insert step 1: Calculate the mass of NaCl in the solution. Assume a total mass of 100 g for simplicity, which means 12.5 g of NaCl and 87.5 g of water.>
<insert step 2: Determine the molality of the solution. Molality (m) is calculated as moles of solute (NaCl) per kilogram of solvent (water).>
<insert step 3: Use the van't Hoff factor (i) for NaCl, which is 2, to account for complete dissociation in the solution.>
<insert step 4: Apply Raoult's Law to find the vapor pressure of water above the solution. Raoult's Law is given by P_solution = X_solvent * P_pure, where X_solvent is the mole fraction of the solvent.>
<insert step 5: Calculate the mass of water in the vapor phase using the ideal gas law or other appropriate methods, considering the vapor pressure and volume of the vapor.>
Related Practice
Textbook Question

A gas has a Henry's law constant of 0.112 M>atm. What total volume of solution is needed to completely dissolve 1.65 L of the gas at a pressure of 725 torr and a temperature of 25 °C?

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Textbook Question

The Safe Drinking Water Act (SDWA) sets a limit for mercury—a toxin to the central nervous system—at 0.0020 ppm by mass. Water suppliers must periodically test their water to ensure that mercury levels do not exceed this limit. Suppose water becomes contaminated with mercury at twice the legal limit (0.0040 ppm). How much of this water would a person have to consume to ingest 50.0 mg of mercury?

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Textbook Question

Water softeners often replace calcium ions in hard water with sodium ions. Since sodium compounds are soluble, the presence of sodium ions in water does not cause the white, scaly residues caused by calcium ions. However, calcium is more beneficial to human health than sodium because calcium is a necessary part of the human diet, while high levels of sodium intake are linked to increases in blood pressure. The U.S. Food and Drug Administration (FDA) recommends that adults ingest less than 2.4 g of sodium per day. How many liters of softened water, containing a sodium concentration of 0.050% sodium by mass, would a person have to consume to exceed the FDA recommendation? (Assume a water density of 1.0 g/mL.)

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Open Question
The vapor above an aqueous solution contains 19.5 mg of water per liter of air at 25 °C. Assuming ideal behavior, what is the mole percent concentration of the solute in the solution?
Open Question
What is the freezing point of an aqueous solution that boils at 106.5 °C?
Textbook Question

An isotonic solution contains 0.90% NaCl mass to volume. Calculate the percent mass to volume for isotonic solutions containing each solute at 25 °C. Assume a van't Hoff factor of 1.9 for all ionic solutes. a. KCl

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