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Ch.14 - Chemical Kinetics
Chapter 14, Problem 75a,b

(a) What is a catalyst? (b) What is the difference between a homogeneous and a heterogeneous catalyst?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Catalyst

A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. It works by providing an alternative reaction pathway with a lower activation energy, allowing reactants to convert to products more efficiently. Catalysts are crucial in both industrial processes and biological systems, where they facilitate reactions that would otherwise occur too slowly.
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Homogeneous Catalyst

A homogeneous catalyst is one that exists in the same phase (solid, liquid, or gas) as the reactants in a chemical reaction. This uniformity allows for better interaction between the catalyst and the reactants, often leading to more efficient reactions. An example is the use of sulfuric acid in the esterification of alcohols, where both the catalyst and reactants are in the liquid phase.
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Heterogeneous Catalyst

A heterogeneous catalyst is one that is in a different phase than the reactants, typically solid catalysts interacting with gaseous or liquid reactants. This phase difference can lead to distinct reaction mechanisms, often involving adsorption of reactants onto the catalyst surface. An example is the use of platinum in catalytic converters, where the solid metal facilitates the conversion of gaseous pollutants into less harmful substances.
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Related Practice
Textbook Question

The reaction 2 NO1g2 + Cl21g2¡2 NOCl1g2 was performed and the following data were obtained under conditions of constant 3Cl24:

(a) Is the following mechanism consistent with the data? NO1g2 + Cl21g2ΔNOCl21g2 1fast2 NOCl21g2 + NO1g2¡2 NOCl1g2 1slow2

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Textbook Question

You have studied the gas-phase oxidation of HBr by O2: 4 HBr(g) + O2(g) → 2 H2O(g) + 2 Br2(g)

You find the reaction to be first order with respect to HBr and first order with respect to O2. You propose the following mechanism:

HBr(g) + O2(g) → HOOBr(g)

HOOBr(g) + HBr(g) → 2 HOBr(g)

HOBr(g) + HBr(g) → H2O(g) + Br2(g)

(a) Confirm that the elementary reactions add to give the overall reaction.

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Textbook Question

You have studied the gas-phase oxidation of HBr by O2: 4 HBr(g) + O2(g) → 2 H2O(g) + 2 Br2(g)

You find the reaction to be first order with respect to HBr and first order with respect to O2. You propose the following mechanism:

HBr(g) + O2(g) → HOOBr(g)

HOOBr(g) + HBr(g) → 2 HOBr(g)

HOBr(g) + HBr(g) → H2O(g) + Br2(g)

(b) Based on the experimentally determined rate law, which step is rate determining?

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Textbook Question

(c) Do catalysts affect the overall enthalpy change for a reaction, the activation energy, or both?

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Textbook Question

(a) Most commercial heterogeneous catalysts are extremely finely divided solid materials. Why is particle size important?

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Open Question
In solution, chemical species as simple as H+ and OH- can serve as catalysts for reactions. Imagine you could measure the [H+] of a solution containing an acid-catalyzed reaction as it occurs. Assume the reactants and products themselves are neither acids nor bases. Sketch the [H+] concentration profile you would measure as a function of time for the reaction, assuming t = 0 is when you add a drop of acid to the reaction.