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12. Solids and Modern Material

Chapter 12, Problem 78

Copper iodide crystallizes in the zinc blende structure. The sep- aration between nearest neighbor cations and anions is approximately 311 pm, and the melting point is 606 °C. Potassium chloride, by contrast, crystallizes in the rock salt structure. Even though the separation between nearest-neighbor cations and anions is greater (319 pm), the melting point of potassium chlo- ride is higher (776 °C). Explain.

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