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Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 93

Air conditioners not only cool air, but dry it as well. A room in a home measures 6.0 m × 10.0 m × 2.2 m. If the outdoor temperature is 30 °C and the partial pressure of water in the air is 85% of the vapor pressure of water at this temperature, what mass of water must be removed from the air each time the volume of air in the room is cycled through the air conditioner? (Assume that all of the water must be removed from the air.) The vapor pressure for water at 30 °C is 31.8 torr.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Vapor Pressure

Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid form at a given temperature. It indicates the tendency of particles to escape from the liquid phase into the gas phase. For water at 30 °C, the vapor pressure is 31.8 torr, meaning that at this temperature, water molecules have a specific tendency to evaporate into the air.
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Relative Humidity

Relative humidity is the ratio of the current amount of water vapor in the air to the maximum amount of water vapor the air can hold at that temperature, expressed as a percentage. In this scenario, the air has a relative humidity of 85%, indicating that it contains 85% of the maximum water vapor capacity at 30 °C. This concept is crucial for determining how much water can be removed from the air.
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Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law can be applied to calculate the amount of water vapor in the air by converting the vapor pressure into moles and then determining the mass of water that corresponds to those moles. Understanding this relationship is essential for solving the problem of how much water must be removed from the air.
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Related Practice
Textbook Question

A sample of steam with a mass of 0.552 g and at a temperature of 100 °C condenses into an insulated container holding 4.25 g of water at 5.0 °C. Assuming that no heat is lost to the surroundings, what is the final temperature of the mixture?

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Open Question
Draw a heating curve (such as the one in Figure 11.36) for 1 mole of methanol beginning at 170 K and ending at 350 K. Assume that the values given here are constant over the relevant temperature ranges. Melting point: 176 K, Boiling point: 338 K, ΔH_fus: 2.2 kJ/mol, ΔH_vap: 35.2 kJ/mol, C_s,solid: 105 J/mol·K, C_s,liquid: 81.3 J/mol·K, C_s,gas: 48 J/mol·K.
Open Question
Draw a heating curve (such as the one in Figure 11.36) for 1 mol of benzene beginning at 0 °C and ending at 100 °C. Assume that the values given here are constant over the relevant temperature ranges: Melting point 5.4 °C, Boiling point 80.1 °C, ΔHfus 9.9 kJ/mol, ΔHvap 30.7 kJ/mol, Cs,solid 118 J/mol⋅K, Cs,liquid 135 J/mol⋅K, Cs,gas 104 J/mol⋅K.
Textbook Question

A sealed flask contains 0.55 g of water at 28 °C. The vapor pressure of water at this temperature is 28.35 mmHg. What is the minimum volume of the flask in order that no liquid water be present in the flask?

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Open Question
Based on the phase diagram of CO2 shown in Figure 11.39(b), describe the state changes that occur when the temperature of CO2 is increased from 190 K to 350 K at a constant pressure of (b) 5.1 atm, (c) 10 atm, and (d) 100 atm.
Textbook Question

Based on the phase diagram of CO2 shown in Figure 11.39(b), describe the state changes that occur when the temperature of CO2 is increased from 190 K to 350 K at a constant pressure of (a) 1 atm

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