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Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 90

A sample of steam with a mass of 0.552 g and at a temperature of 100 °C condenses into an insulated container holding 4.25 g of water at 5.0 °C. Assuming that no heat is lost to the surroundings, what is the final temperature of the mixture?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Heat Transfer and Conservation of Energy

In thermodynamics, the principle of conservation of energy states that energy cannot be created or destroyed, only transformed. In this scenario, the heat lost by the steam as it condenses and cools must equal the heat gained by the water as it warms up. This relationship allows us to set up an equation to solve for the final temperature of the mixture.
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Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. Different substances have different specific heat capacities, which affect how they respond to heat transfer. In this problem, the specific heat capacities of steam and water will be crucial for calculating the heat exchange during the condensation and warming processes.
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Phase Change and Latent Heat

Phase changes, such as the condensation of steam into water, involve latent heat, which is the heat absorbed or released during a phase transition without a change in temperature. The latent heat of vaporization for water is significant in this problem, as it quantifies the energy released when steam condenses. Understanding this concept is essential for accurately calculating the heat transfer involved in the process.
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Related Practice
Open Question
Examine the phase diagram for iodine shown in Figure 11.39(a). What state transitions occur as we uniformly increase the pressure on a gaseous sample of iodine from 0.010 atm at 185 °C to 100 atm at 185 °C?
Open Question
Carbon tetrachloride displays a triple point at 249.0 K and a melting point (at 1 atm) of 250.3 K. Which state of carbon tetrachloride is more dense, the solid or the liquid, and why?
Open Question
Four ice cubes at exactly 0 °C with a total mass of 53.5 g are combined with 115 g of water at 75 °C in an insulated container. If no heat is lost to the surroundings, what is the final temperature of the mixture?
Open Question
Draw a heating curve (such as the one in Figure 11.36) for 1 mole of methanol beginning at 170 K and ending at 350 K. Assume that the values given here are constant over the relevant temperature ranges. Melting point: 176 K, Boiling point: 338 K, ΔH_fus: 2.2 kJ/mol, ΔH_vap: 35.2 kJ/mol, C_s,solid: 105 J/mol·K, C_s,liquid: 81.3 J/mol·K, C_s,gas: 48 J/mol·K.
Open Question
Draw a heating curve (such as the one in Figure 11.36) for 1 mol of benzene beginning at 0 °C and ending at 100 °C. Assume that the values given here are constant over the relevant temperature ranges: Melting point 5.4 °C, Boiling point 80.1 °C, ΔHfus 9.9 kJ/mol, ΔHvap 30.7 kJ/mol, Cs,solid 118 J/mol⋅K, Cs,liquid 135 J/mol⋅K, Cs,gas 104 J/mol⋅K.
Textbook Question

Air conditioners not only cool air, but dry it as well. A room in a home measures 6.0 m × 10.0 m × 2.2 m. If the outdoor temperature is 30 °C and the partial pressure of water in the air is 85% of the vapor pressure of water at this temperature, what mass of water must be removed from the air each time the volume of air in the room is cycled through the air conditioner? (Assume that all of the water must be removed from the air.) The vapor pressure for water at 30 °C is 31.8 torr.

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