Skip to main content
Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
Chapter 8, Problem 34

Ethyl acetate, CH3CO2CH2CH3, is commonly used as a solvent and nail-polish remover. Look at the following electrostatic potential map of ethyl acetate, and explain the observed polarity.
Electrostatic potential map of ethyl acetate showing molecular polarity with color gradients.

Verified step by step guidance
1
Observe the electrostatic potential map of ethyl acetate. The color gradient indicates the distribution of electron density across the molecule.
Identify the regions of high electron density (red) and low electron density (blue). In the image, the red region is around the oxygen atom, indicating a high electron density.
Note that the blue region around the hydrogen atoms indicates a low electron density. This suggests that the oxygen atom is more electronegative and pulls electron density towards itself.
Understand that the difference in electron density creates a dipole moment, with the oxygen atom having a partial negative charge (δ-) and the hydrogen atoms having a partial positive charge (δ+).
Conclude that the observed polarity in ethyl acetate is due to the electronegativity difference between the oxygen and hydrogen atoms, resulting in a polar molecule with a dipole moment directed from the hydrogen atoms towards the oxygen atom.

Verified Solution

Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molecular Polarity

Molecular polarity arises from the distribution of electron density within a molecule, leading to regions of partial positive and negative charge. In ethyl acetate, the presence of polar bonds, particularly between carbon and oxygen, creates a dipole moment, making the molecule polar. This polarity affects the molecule's interactions with other substances, influencing its behavior as a solvent.
Recommended video:
Guided course
02:38
Molecular Polarity

Electrostatic Potential Map

An electrostatic potential map visually represents the charge distribution within a molecule, using color gradients to indicate areas of positive and negative potential. In the case of ethyl acetate, the map shows regions where electron density is higher (negative potential) and lower (positive potential), helping to illustrate the molecule's polarity and how it interacts with other molecules.
Recommended video:
Guided course
00:34
Kinetic & Potential Energy

Functional Groups

Functional groups are specific groups of atoms within molecules that determine their chemical properties and reactivity. Ethyl acetate contains an ester functional group (–COO–), which contributes to its polarity and solubility characteristics. Understanding functional groups is essential for predicting the behavior of organic compounds in various chemical contexts.
Recommended video:
Guided course
01:32
Carbonyl Functional Groups
Related Practice
Textbook Question

The following ball-and-stick molecular model is a representation of acetaminophen, the active ingredient in such over-thecounter headache remedies as Tylenol. (Red = O, gray = C, blue = N, ivory = H.) (a) What is the formula of acetaminophen?

556
views
Textbook Question

The following ball-and-stick molecular model is a representation of acetaminophen, the active ingredient in such over-thecounter headache remedies as Tylenol. (Red = O, gray = C, blue = N, ivory = H.) (b) Indicate the positions of the multiple bonds in acetaminophen.

814
views
Textbook Question

The following ball-and-stick molecular model is a representation of thalidomide, a drug that causes birth defects when taken by expectant mothers but is valuable for its use against leprosy. The lines indicate only the connections between atoms, not whether the bonds are single, double, or triple. 1Red = O, gray = C, blue = N, ivory = H.2 (a) What is the formula of thalidomide?

332
views
Textbook Question

Two dichloroethylene molecules with the same chemical formula 1C2H2Cl22, but different arrangements of atoms are shown. (b) Which form of dichloroethylene has a dipole moment of 2.39 D, and which has a dipole moment of 0.00 D?

371
views
Textbook Question
What geometric arrangement of charge clouds do you expect for atoms that have the following number of charge clouds? (a) 3 (b) 5 (c) 2 (d) 6
510
views
Textbook Question
What shape do you expect for molecules that meet the following descriptions? (a) A central atom with two lone pairs and three bonds to other atoms (b) A central atom with two lone pairs and two bonds to other atoms (c) A central atom with two lone pairs and four bonds to other atoms
603
views