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Ch.10 - Gases: Their Properties & Behavior
Chapter 10, Problem 26a

Assume that you have a sample of gas in a cylinder with a movable piston, as shown in the following drawing:
Illustration of a gas cylinder with a movable piston, showing gas particles at increased temperature.
Redraw the apparatus to show what the sample will look like after (a) the temperature is increased from 300 K to 450 K at constant pressure

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law helps predict how a gas will behave under different conditions, making it essential for understanding gas behavior in the given scenario.
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Charles's Law

Charles's Law states that the volume of a gas is directly proportional to its temperature when pressure is held constant. Mathematically, it can be expressed as V1/T1 = V2/T2. This principle is crucial for the question, as it allows us to determine how the volume of the gas will change when the temperature is increased from 300 K to 450 K while maintaining constant pressure.
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Kinetic Molecular Theory

The Kinetic Molecular Theory explains the behavior of gases in terms of the motion of their particles. It posits that gas particles are in constant, random motion and that temperature is a measure of the average kinetic energy of these particles. As the temperature increases, the kinetic energy of the gas particles also increases, leading to greater movement and expansion of the gas, which is relevant for visualizing the changes in the gas sample when heated.
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Related Practice
Textbook Question
An unknown gas is found to diffuse through a porous membrane 2.92 times more slowly than H2. What is the molecular weight of the gas? (a) 17.0 g/mol (b) 5.84 g/mol (c) 8.52 g/mol
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Textbook Question
Identify the true statement about deviations from ideal gas behavior. (LO 10.12) (a) The attractive forces between gas particles cause the true volume of the sample to be larger than predicted by the ideal gas law. (b) The attractive forces between gas particles most influence the volume of a sample at low pressure. (c) The volume of the gas particles themselves most influences the volume of the sample at low pressure. (d) The volume of the gas particles themselves causes the true volume of the sample to be larger than predicted by the ideal gas law.
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Textbook Question
A glass tube has one end in a dish of mercury and the other end closed by a stopcock. The distance from the surface of the mercury to the bottom of the stopcock is 850 mm. The apparatus is at 25 °C, and the mercury level in the tube is the same as that in the dish.

(a) Show on drawing (1) what the approximate level of mercury in the tube will be when the temperature of the entire apparatus is lowered from +25 °C to -25 °C.
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Textbook Question

Assume that you have a sample of gas in a cylinder with a movable piston, as shown in the following drawing:

Redraw the apparatus to show what the sample will look like after (b) the pressure is increased from 1 atm to 2 atm at constant temperature

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Textbook Question

Assume that you have a sample of gas in a cylinder with a movable piston, as shown in the following drawing:

Redraw the apparatus to show what the sample will look like after (c) the temperature is decreased from 300 K to 200 K and the pressure is decreased from 3 atm to 2 atm.

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Textbook Question
Show the approximate level of the movable piston in drawings (a), (b), and (c) after the indicated changes have been made to the gas.

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