Chapter 15, Problem 14b
The equilibrium constant for the dissociation of molecular iodine, I2(π) β 2 I(π), at 800 K is πΎπ = 3.1Γ10β5. (b) Assuming both forward and reverse reactions are elementary reactions, which reaction has the larger rate constant, the forward or the reverse reaction?
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The reaction A2 + B2 β 2 AB has an equilibrium constant Kc = 1.5. The following diagrams represent reaction mixtures containing A2 molecules (red), B2 molecules (blue), and AB molecules. (a) Which reaction mixture is at equilibrium?
The diagram shown here represents the equilibrium state for the reaction A2(π) + 2B(π) β 2AB(π). (a) Assuming the volume is 2 L, calculate the equilibrium constant πΎπ for the reaction.
Suppose that the gas-phase reactions A β B and B β A are both elementary reactions with rate constants of 4.7Γ10β3β sβ1 and 5.8Γ10β1 sβ1, respectively. (b) Which is greater at equilibrium, the partial pressure of A or the partial pressure of B?
Write the expression for πΎπ for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous.
(e) 2Ag(π ) + Zn2+(ππ) β 2 Ag+(ππ) + Zn(π )
Write the expressions for πΎπ for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous.
(b) Ti(π ) + 2Cl2(π) β TiCl4(π)
Write the expressions for πΎπ for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous. (g) 2 C8H18(π) + 25 O2(π) β 16 CO2(π) + 18 H2O(π)