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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 14b

The equilibrium constant for the dissociation of molecular iodine, I2(𝑔) β‡Œ 2 I(𝑔), at 800 K is 𝐾𝑐 = 3.1Γ—10βˆ’5. (b) Assuming both forward and reverse reactions are elementary reactions, which reaction has the larger rate constant, the forward or the reverse reaction?

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Hi everyone. So as to consider the following reaction below where the K value was eight times 10 to the eight. We were asked to determine whether the four or the reverse reaction has a larger rate constant, assuming that both reactions are elementary reactions. To determine this, we need to look at the equilibrium constant K equilibrium concept. It was the right concept for the forward reaction by by the rate constant for the reverse reaction. Okay, it's gonna be greater than one if the right constant of the forward reaction is greater than the rate constant of the reverse reaction. So this means we have a bigger number on top and we divided by a smaller number on the bottom. And if K is less than one, the rate constant of the forward reaction gonna be less than the rate constant of the reverse reaction. So this means we have a small number on top, divided by a bigger number on the bottom, since K equals eight Times 10 to the eight And eight times 10 to the eight is greater than one. This means that the full reaction has a larger rate constant in a reverse reaction. Thanks for watching my video and I hope it was helpful
Related Practice
Textbook Question

The reaction A2 + B2 β‡Œ 2 AB has an equilibrium constant Kc = 1.5. The following diagrams represent reaction mixtures containing A2 molecules (red), B2 molecules (blue), and AB molecules. (a) Which reaction mixture is at equilibrium?

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Textbook Question

The diagram shown here represents the equilibrium state for the reaction A2(𝑔) + 2B(𝑔) β‡Œ 2AB(𝑔). (a) Assuming the volume is 2 L, calculate the equilibrium constant 𝐾𝑐 for the reaction.

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Textbook Question

Suppose that the gas-phase reactions A β†’ B and B β†’ A are both elementary reactions with rate constants of 4.7Γ—10βˆ’3β€Š sβˆ’1 and 5.8Γ—10βˆ’1 sβˆ’1, respectively. (b) Which is greater at equilibrium, the partial pressure of A or the partial pressure of B?

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Textbook Question

Write the expression for 𝐾𝑐 for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous.

(e) 2Ag(𝑠) + Zn2+(π‘Žπ‘ž) β‡Œ 2 Ag+(π‘Žπ‘ž) + Zn(𝑠)

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Textbook Question

Write the expressions for 𝐾𝑐 for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous.

(b) Ti(𝑠) + 2Cl2(𝑔) β‡Œ TiCl4(𝑙)

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Textbook Question

Write the expressions for 𝐾𝑐 for the following reactions. In each case indicate whether the reaction is homogeneous or heterogeneous. (g) 2 C8H18(𝑙) + 25 O2(𝑔) β‡Œ 16 CO2(𝑔) + 18 H2O(𝑙)

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