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Ch 18: Thermal Properties of Matter
Chapter 18, Problem 18

How Close Together Are Gas Molecules? Consider an ideal gas at 27°C and 1.00 atm. To get some idea how close these molecules are to each other, on the average, imagine them to be uniformly spaced, with each molecule at the center of a small cube. (a) What is the length of an edge of each cube if adjacent cubes touch but do not overlap?

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Convert the temperature from Celsius to Kelvin by adding 273.15 to the Celsius temperature. This is necessary because the ideal gas law requires temperature in Kelvin.
Use the ideal gas law, PV = nRT, to find the volume occupied by one mole of the gas. Here, P is the pressure, V is the volume, n is the number of moles, R is the gas constant (0.0821 L atm K^{-1} mol^{-1}), and T is the temperature in Kelvin.
Calculate the volume occupied by one molecule by dividing the molar volume by Avogadro's number (approximately 6.022 \times 10^{23} molecules/mol). This gives the volume of the cube in which one molecule is located.
Find the length of an edge of the cube by taking the cube root of the volume calculated in the previous step. This length represents the average distance between the centers of adjacent molecules when they are imagined to be at the centers of touching cubes.
Interpret the result as the average distance between molecules in an ideal gas under the given conditions, keeping in mind that this is a simplified model and actual distances may vary due to molecular motion and interactions.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in thermodynamics that relates the pressure, volume, temperature, and number of moles of an ideal gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law helps in understanding the behavior of gas molecules under various conditions.
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Molecular Spacing

Molecular spacing refers to the average distance between gas molecules in a given volume. In an ideal gas, molecules are assumed to be point particles that do not interact with each other except during elastic collisions. Understanding molecular spacing is crucial for visualizing how gas molecules are distributed in space and how they occupy volume.
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Volume of a Cube

The volume of a cube is calculated using the formula V = a³, where 'a' is the length of one edge of the cube. In the context of gas molecules, if we consider each molecule to be at the center of a cube, the edge length can be determined by dividing the total volume occupied by the gas by the number of molecules. This concept is essential for determining how closely packed the gas molecules are.
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Related Practice
Textbook Question
Modern vacuum pumps make it easy to attain pressures of the order of 10^-13 atm in the laboratory. Consider a volume of air and treat the air as an ideal gas. (a) At a pressure of 9.00 * 10^-14 atm and an ordinary temperature of 300.0 K, how many molecules are present in a volume of 1.00 cm^3?
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Textbook Question
Modern vacuum pumps make it easy to attain pressures of the order of 10^-13 atm in the laboratory. Consider a volume of air and treat the air as an ideal gas. (b) How many molecules would be present at the same temperature but at 1.00 atm instead?
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Textbook Question
In a gas at standard conditions, what is the length of the side of a cube that contains a number of molecules equal to the population of the earth (about 7 * 10^9 people)?
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Textbook Question
Meteorology. The vapor pressure is the pressure of the vapor phase of a substance when it is in equilibrium with the solid or liquid phase of the substance. The relative humidity is the partial pressure of water vapor in the air divided by the vapor pressure of water at that same temperature, expressed as a percentage. The air is saturated when the humidity is 100%. (a) The vapor pressure of water at 20.0°C is 2.34 * 10^3 Pa. If the air temperature is 20.0°C and the relative humidity is 60%, what is the partial pressure of water vapor in the atmosphere (that is, the pressure due to water vapor alone)?
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Textbook Question
How much heat does it take to increase the temperature of 1.80 mol of an ideal gas by 50.0 K near room temperature if the gas is held at constant volume and is (a) diatomic;
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Textbook Question
How much heat does it take to increase the temperature of 1.80 mol of an ideal gas by 50.0 K near room temperature if the gas is held at constant volume and is (b) monatomic?
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