The thermal energy of 1.0 mol of a substance is increased by 1.0 J. What is the temperature change if the system is (a) a monatomic gas, (b) a diatomic gas, and (c) a solid?
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1
Identify the type of substance and the corresponding degrees of freedom. For a monatomic gas, there are 3 translational degrees of freedom. For a diatomic gas, there are 5 degrees of freedom (3 translational and 2 rotational). For a solid, typically, all 3 translational and 3 vibrational degrees of freedom are considered, totaling 6 degrees of freedom.
Use the formula for the molar specific heat capacity at constant volume, $C_V = \frac{f}{2} R$, where $f$ is the degrees of freedom and $R$ is the gas constant (approximately 8.314 J/mol\cdot K).
Calculate the specific heat capacity for each case: (a) monatomic gas, (b) diatomic gas, and (c) solid, using their respective degrees of freedom.
Apply the formula for change in temperature, $\Delta T = \frac{\Delta Q}{n C_V}$, where $\Delta Q$ is the change in thermal energy, $n$ is the number of moles, and $C_V$ is the specific heat capacity at constant volume. Here, $\Delta Q = 1.0 \text{ J}$ and $n = 1.0 \text{ mol}$.
Calculate the temperature change $\Delta T$ for each case using the specific heat capacities found in step 3 and the formula from step 4.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Heat Capacity
Heat capacity is the amount of heat energy required to change the temperature of a substance by a certain amount. It varies depending on the substance's phase and molecular structure. For gases, the heat capacity can differ based on whether the gas is monatomic or diatomic, affecting how temperature changes with added thermal energy.
Degrees of freedom refer to the number of independent ways in which a system can store energy. Monatomic gases have three translational degrees of freedom, while diatomic gases have additional rotational degrees of freedom. This difference influences how much temperature changes when energy is added, as more degrees of freedom allow for greater energy distribution.
Specific heat is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. Different materials have different specific heats, which affect how they respond to added thermal energy. Solids typically have lower specific heats compared to gases, leading to different temperature changes for the same amount of energy input.