Photons of light scatter off molecules, and the distance you can see through a gas is proportional to the mean free path of photons through the gas. Photons are not gas molecules, so the mean free path of a photon is not given by Equation 20.3, but its dependence on the number density of the gas and on the molecular radius is the same. Suppose you are in a smoggy city and can barely see buildings 500 m away.
a. How far would you be able to see if all the molecules around you suddenly doubled in volume?
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Identify the relationship between the molecular volume and the mean free path. The mean free path (λ) is inversely proportional to the cross-sectional area of the molecules, which is related to the square of the radius (r^2). If the volume of the molecules doubles, the radius increases by the cube root of 2, i.e., r' = r \times \sqrt[3]{2}.
Calculate the new cross-sectional area using the new radius. Since the area (A) is proportional to r^2, the new area A' will be A' = (r \times \sqrt[3]{2})^2 = r^2 \times (\sqrt[3]{2})^2.
Determine the new mean free path λ' using the relationship λ' = λ / (\sqrt[3]{2})^2. This is because the mean free path is inversely proportional to the cross-sectional area.
Apply the proportionality of visibility distance to the mean free path. Since the visibility distance is directly proportional to the mean free path, the new visibility distance d' can be calculated as d' = d / (\sqrt[3]{2})^2, where d is the original visibility distance (500 m).
Conclude that the visibility distance will decrease due to the increase in molecular volume, and calculate the new visibility distance using the formula derived in the previous step.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Mean Free Path
The mean free path is the average distance a particle travels between collisions with other particles. In the context of photons scattering off gas molecules, it describes how far a photon can travel before interacting with a molecule. This distance is influenced by the number density of the gas and the size of the molecules, which affects the likelihood of scattering events.
Number density refers to the number of particles per unit volume in a given space. In this scenario, it is crucial because as the volume of gas doubles, the number density of gas molecules decreases, affecting the mean free path of photons. A lower number density means fewer molecules are present to scatter the photons, allowing them to travel further before being obstructed.
Scattering of photons occurs when light interacts with particles, causing the light to change direction. This phenomenon is significant in determining visibility in a medium like smog, where the presence of gas molecules scatters light and reduces the distance one can see. The extent of scattering is influenced by the properties of the gas and the wavelength of the light, impacting how far light can travel through the medium.