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Ch 20: The Micro/Macro Connection
Chapter 20, Problem 20

Photons of light scatter off molecules, and the distance you can see through a gas is proportional to the mean free path of photons through the gas. Photons are not gas molecules, so the mean free path of a photon is not given by Equation 20.3, but its dependence on the number density of the gas and on the molecular radius is the same. Suppose you are in a smoggy city and can barely see buildings 500 m away. a. How far would you be able to see if all the molecules around you suddenly doubled in volume?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Mean Free Path

The mean free path is the average distance a particle travels between collisions with other particles. In the context of photons scattering off gas molecules, it describes how far a photon can travel before interacting with a molecule. This distance is influenced by the number density of the gas and the size of the molecules, which affects the likelihood of scattering events.
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Number Density

Number density refers to the number of particles per unit volume in a given space. In this scenario, it is crucial because as the volume of gas doubles, the number density of gas molecules decreases, affecting the mean free path of photons. A lower number density means fewer molecules are present to scatter the photons, allowing them to travel further before being obstructed.
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Scattering of Photons

Scattering of photons occurs when light interacts with particles, causing the light to change direction. This phenomenon is significant in determining visibility in a medium like smog, where the presence of gas molecules scatters light and reduces the distance one can see. The extent of scattering is influenced by the properties of the gas and the wavelength of the light, impacting how far light can travel through the medium.
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Related Practice
Textbook Question
The mean free path of a molecule in a gas is 300 nm. What will the mean free path be if the gas temperature is doubled at (a) constant volume and (b) constant pressure?
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Textbook Question
Integrated circuits are manufactured in vacuum chambers in which the air pressure is 1.0 x 10⁻¹⁰ of Hg. What are (a) the number density and (b) the mean free path of a molecule? Assume T = 20℃.
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Textbook Question
A mad engineer builds a cube, 2.5 m on a side, in which 6.2-cm-diameter rubber balls are constantly sent flying in random directions by vibrating walls. He will award a prize to anyone who can figure out how many balls are in the cube without entering it or taking out any of the balls. You decide to shoot 6.2-cm-diameter plastic balls into the cube, through a small hole, to see how far they get before colliding with a rubber ball. After many shots, you find they travel an average distance of 1.8 m. How many rubber balls do you think are in the cube?
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Textbook Question
On earth, STP is based on the average atmospheric pressure at the surface and on a phase change of water that occurs at an easily produced temperature, being only slightly cooler than the average air temperature. The atmosphere of Venus is almost entirely carbon dioxide (CO₂), the pressure at the surface is a staggering 93 atm, and the average temperature is 470℃. Venusian scientists, if they existed, would certainly use the surface pressure as part of their definition of STP. To complete the definition, they would seek a phase change that occurs near the average temperature. Conveniently, the melting point of the element tellurium is 450℃. What are (a) the rms speed and (b) the mean free path of carbon dioxide molecules at Venusian STP based on this phase change in tellurium? The radius of a CO₂ molecule is 1.5 x 10⁻¹⁰ m.
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Textbook Question
1.0 mol of argon has 3100 J of thermal energy. What is the gas temperature in °C?
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Textbook Question
Liquid helium boils at 4.2 K. In a flask, the helium gas above the boiling liquid is at the same temperature. What are (a) the mean free path in the gas, (b) the rms speed of the atoms, and (c) the average energy per atom?
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