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Ch 20: The Micro/Macro Connection
Chapter 20, Problem 20

Integrated circuits are manufactured in vacuum chambers in which the air pressure is 1.0 x 10⁻¹⁰ of Hg. What are (a) the number density and (b) the mean free path of a molecule? Assume T = 20℃.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Number Density

Number density refers to the number of particles (molecules, atoms, etc.) per unit volume in a given space. It is typically expressed in units such as particles per cubic meter. In the context of the question, calculating the number density of air molecules at a specific pressure involves using the ideal gas law, which relates pressure, volume, and temperature to the number of particles.
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Mean Free Path

The mean free path is the average distance a molecule travels between collisions with other molecules. It is influenced by the number density of the gas and the size of the molecules. In low-pressure environments, such as the vacuum chambers mentioned, the mean free path increases significantly, allowing molecules to travel longer distances without colliding, which is crucial for the manufacturing processes of integrated circuits.
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Ideal Gas Law

The ideal gas law is a fundamental equation in thermodynamics that describes the behavior of ideal gases. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law allows us to relate the pressure and temperature of a gas to its number density, which is essential for solving the problem presented in the question.
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Related Practice
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On earth, STP is based on the average atmospheric pressure at the surface and on a phase change of water that occurs at an easily produced temperature, being only slightly cooler than the average air temperature. The atmosphere of Venus is almost entirely carbon dioxide (CO₂), the pressure at the surface is a staggering 93 atm, and the average temperature is 470℃. Venusian scientists, if they existed, would certainly use the surface pressure as part of their definition of STP. To complete the definition, they would seek a phase change that occurs near the average temperature. Conveniently, the melting point of the element tellurium is 450℃. What are (a) the rms speed and (b) the mean free path of carbon dioxide molecules at Venusian STP based on this phase change in tellurium? The radius of a CO₂ molecule is 1.5 x 10⁻¹⁰ m.
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