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Ch 20: The Micro/Macro Connection
Chapter 20, Problem 20

Eleven molecules have speeds 15, 16, 17, …, 25 m/s. Calculate (a) vₐᵥ₉ and (b) vᵣₘₛ.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Average Speed (vₐᵥ₉)

Average speed is calculated by taking the sum of all individual speeds and dividing it by the number of observations. In this case, for the eleven molecules with speeds ranging from 15 to 25 m/s, the average speed can be found by summing these speeds and dividing by 11. This provides a measure of the central tendency of the speeds.
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Root Mean Square Speed (vᵣₘₛ)

Root mean square speed is a statistical measure of the speed of particles in a gas. It is calculated by taking the square root of the average of the squares of the speeds. This concept is particularly useful in kinetic theory, as it relates to the energy and temperature of the gas, providing insight into the motion of the molecules.
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Kinetic Theory of Gases

The kinetic theory of gases explains the behavior of gases in terms of the motion of their molecules. It posits that gas molecules are in constant random motion and that their speeds contribute to the pressure and temperature of the gas. Understanding this theory is essential for interpreting the significance of average and root mean square speeds in the context of molecular motion.
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Related Practice
Textbook Question
The 2010 Nobel Prize in Physics was awarded for the discovery of graphene, a two-dimensional form of carbon in which the atoms form a two-dimensional crystal-lattice sheet only one atom thick. Predict the molar specific heat of graphene. Give your answer as a multiple of R.
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Textbook Question
Consider a container like that shown in Figure 20.12, with n₁ moles of a monatomic gas on one side and n₂ moles of a diatomic gas on the other. The monatomic gas has initial temperature T₁ᵢ. The diatomic gas has initial temperature T₂ᵢ. a. Show that the equilibrium thermal energies are
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Textbook Question
You are watching a science fiction movie in which the hero shrinks down to the size of an atom and fights villains while jumping from air molecule to air molecule. In one scene, the hero's molecule is about to crash head-on into the molecule on which a villain is riding. The villain's molecule is initially 50 molecular radii away and, in the movie, it takes 3.5 s for the molecules to collide. Estimate the air temperature required for this to be possible. Assume the molecules are nitrogen molecules, each traveling at the rms speed. Is this a plausible temperature for air?
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Textbook Question
b. A gas cylinder has a piston at one end that is moving outward at speed vₚᵢₛₜₒₙ during an isobaric expansion of the gas. Find an expression for the rate at which vᵣₘₛ is changing in terms of vₚᵢₛₜₒₙ, the instantaneous value of vᵣₘₛ, and the instantaneous value L of the length of the cylinder.
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Textbook Question
Uranium has two naturally occurring isotopes. ²³⁸U has a natural abundance of 99.3% and ²³⁵U has an abundance of 0.7%. It is the rarer ²³⁵U that is needed for nuclear reactors. The isotopes are separated by forming uranium hexafluoride, UF₆, which is a gas, then allowing it to diffuse through a series of porous membranes. ²³⁵UF₆ has a slightly larger rms speed than ²³⁸UF₆ and diffuses slightly faster. Many repetitions of this procedure gradually separate the two isotopes. What is the ratio of the rms speed of ²³⁵UF₆ to that of ²³⁸UF₆?
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Textbook Question
A cylinder contains gas at a pressure of 2.0 atm and a number density of 4.2 x 10²⁵ m⁻³. The rms speed of the atoms is 660 m/s. Identify the gas.
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