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Ch 20: The Micro/Macro Connection
Chapter 20, Problem 20

A cylinder of nitrogen and a cylinder of neon are at the same temperature and pressure. The mean free path of a nitrogen molecule is 150 nm. What is the mean free path of a neon atom?

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Identify that the mean free path (\(\lambda\)) of a gas molecule is inversely proportional to the number density (\(n\)) of the gas and the cross-sectional area (\(\sigma\)) of the molecule. The formula is given by \(\lambda = \frac{1}{n \sigma}\).
Recognize that both gases are at the same temperature and pressure, which implies that their number densities (\(n\)) are equal, assuming ideal gas behavior.
Understand that the mean free path is also influenced by the cross-sectional area (\(\sigma\)) of the molecules. Since nitrogen (\(N_2\)) is a diatomic molecule and neon (\(Ne\)) is a monoatomic gas, their molecular structures and sizes differ, affecting \(\sigma\).
Since the number densities are the same, the ratio of the mean free paths of nitrogen and neon will be inversely proportional to the ratio of their cross-sectional areas. Thus, \(\frac{\lambda_{Ne}}{\lambda_{N_2}} = \frac{\sigma_{N_2}}{\sigma_{Ne}}\).
Calculate the mean free path of neon by rearranging the formula to \(\lambda_{Ne} = \lambda_{N_2} \times \frac{\sigma_{N_2}}{\sigma_{Ne}}\) and substituting the known values and estimated cross-sectional area ratios.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Mean Free Path

The mean free path is the average distance a particle travels between collisions with other particles. It is influenced by the density of the gas and the size of the particles. In gases, a longer mean free path indicates fewer collisions, while a shorter mean free path suggests more frequent interactions.
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Kinetic Theory of Gases

The kinetic theory of gases describes the behavior of gases in terms of particles in constant motion. It explains how temperature, pressure, and volume relate to the motion and collisions of gas molecules. This theory helps in understanding properties like mean free path, as it connects molecular speed and collision frequency.
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Gas Properties and Molecular Size

Different gases have distinct molecular sizes and masses, which affect their mean free paths. Lighter and smaller molecules, like neon, typically have longer mean free paths than heavier molecules, assuming similar conditions. Understanding these properties is crucial for comparing the behavior of different gases under the same temperature and pressure.
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