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Ch.23 Lipids
Chapter 23, Problem 23.51

Tell how many different products you would obtain on hydrogenation of the triacylglycerol in Problem 23.49 if:


a. One double bond was converted to a single bond
b. Two double bonds were converted to single bonds
c. Three double bonds were converted to single bonds
d. All four double bonds were converted to single bonds

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1
<insert step 1> Identify the structure of the triacylglycerol in Problem 23.49, noting the number and position of double bonds in the fatty acid chains.
<insert step 2> For part (a), consider the possible products when one double bond is hydrogenated. Determine how many different fatty acid chains can result from this change.
<insert step 3> For part (b), analyze the scenario where two double bonds are hydrogenated. Consider the combinations of double bonds that can be converted and the resulting different products.
<insert step 4> For part (c), evaluate the situation where three double bonds are hydrogenated. Identify the possible combinations and resulting products.
<insert step 5> For part (d), consider the complete hydrogenation of all four double bonds and determine the number of distinct products that can be formed.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Triacylglycerol Structure

Triacylglycerols, or triglycerides, are esters formed from glycerol and three fatty acids. The fatty acids can contain one or more double bonds, which influence the physical properties and reactivity of the molecule. Understanding the structure of triacylglycerols is essential for predicting the products of hydrogenation, as the number and position of double bonds determine how many hydrogen atoms can be added.
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Hydrogenation Process

Hydrogenation is a chemical reaction that involves the addition of hydrogen (H2) to unsaturated bonds, typically double bonds in fatty acids. This process converts double bonds into single bonds, resulting in a more saturated fat. The extent of hydrogenation affects the number of products formed, as each double bond that is hydrogenated can lead to different structural isomers depending on the original configuration of the fatty acids.
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Isomer Formation

Isomer formation refers to the creation of different structural forms of a compound that have the same molecular formula but different arrangements of atoms. In the context of hydrogenation of triacylglycerols, the conversion of double bonds to single bonds can lead to various isomers, depending on the original configuration of the fatty acids. Understanding isomer formation is crucial for predicting the diversity of products resulting from the hydrogenation process.
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