17. Amines

Write the structures of the following compounds:

a. Butyldiethylammonium bromide

Write the structure of benzylamine hydrochloride in two different ways, and name the hydrochloride as an ammonium salt.

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Give names or structures for the following ammonium salts. Indicate whether each is the ammonium salt of a primary, secondary, or tertiary amine.

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Give names or structures for the following ammonium salts. Indicate whether each is the ammonium salt of a primary, secondary, or tertiary amine.

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Give names or structures for the following ammonium salts. Indicate whether each is the ammonium salt of a primary, secondary, or tertiary amine.

c. N-Butyl-N-isopropylhexylammonium chloride

Draw structure for N,N-diethyl-2-hexanaminium.

Draw structure for propylammonium ion.

Provide the IUPAC name for the following ammonium salt.

Which of the following represents m-bromo-N-ethyl-N-isopropylbenzenaminium?

Draw the condensed structural or line-angle formula if cyclic, for each of the following: (14.5)

d. ethylmethylammonium bromide

Novocain, a local anesthetic, is the ammonium salt of procaine. (14.5)

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a. Draw the condensed structural formula for the ammonium salt (procaine hydrochloride) formed when procaine reacts with HCl. (Hint: The tertiary amine reacts with HCl.)

Lidocaine (xylocaine) is used as a local anesthetic and cardiac depressant. (14.5)

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a. Draw the condensed structural formula for the ammonium salt formed when lidocaine reacts with HCl.