14. Compounds with Oxygen or Sulfur

Provide the systematic name for the following alcohol.

Provide the formal name for the following alcohol. 

Which structure represents 2-bromo-2,3-dichloro-1-heptanol?

Name the following dialcohol.

Provide IUPAC name for the following trialcohol.

Label each alcohol as primary, secondary, or tertiary.

Name the following compounds:

a. <IMAGE>

b. <IMAGE>

Draw structures for the following:

a. 2,4-Dinitrophenol

b. m-Ethylphenol

Draw structures corresponding to the following names:

b. 2,2-Diethylcyclohexanol

Draw structures corresponding to the following names:

a. 2,4-Dimethyl-2-heptanol

Draw all possible cyclic C₇H₁₄O alcohol isomers having a cyclohexane ring and a methyl group. (Hint: Adapt the method described in Worked Example 12.12 to arrive at your answers.)

Name the following compounds:

c. <IMAGE>

d. <IMAGE>

a. Identify each alcohol named in Problem 14.32 as primary, secondary, or tertiary.

Draw structures corresponding to the following names:

e. 2,4-Dimethoxy-3-methylpentane

Draw structures corresponding to the following names:

f. 3,3-Dimethyl-1,6-heptanediol

Write the formulas and IUPAC names for the following common alcohols (Hint: See Table 14.1).

a. Rubbing alcohol

Write the formulas and IUPAC names for the following common alcohols (Hint: See Table 14.1).

d. Diol used as antifreeze (two answers)

Give the IUPAC name for each of the following:

d. <IMAGE>

Give the IUPAC name for each of the following:

b. <IMAGE>

Give the IUPAC name for each of the following alcohols and phenols: (12.1)

a. <IMAGE>

Draw the condensed structural formula, or line-angle formula if cyclic, for each of the following:

d. 4-bromophenol

Classify each of the following alcohols as primary (1°), secondary (2°), or tertiary (3°):

a. <IMAGE>

Write the balanced chemical equation for the complete combustion of each of the following compounds:

b. 3-hexanol

Draw the condensed structural or line-angle formula for each of the following: (12.1)

b. 2-methyl-3-pentanol

Draw the condensed structural or line-angle formula for each of the following: (12.1)

d. 2,4-dibromophenol

Draw the condensed structural formulas and give the IUPAC names for all the alcohols that have the formula C₅H₁₂O. (12.1)

Classify each of the following alcohols as primary (1°), secondary (2°), or tertiary (3°):

c. <IMAGE>

Classify each of the following alcohols as primary (1°), secondary (2°), or tertiary (3°):

d. <IMAGE>

Draw the condensed structural formula, or line-angle formula if cyclic, for each of the following:

c. 2-methyl-2-butanol

Classify each of the following alcohols as primary (1°), secondary (2°), or tertiary (3°):

d. <IMAGE>

Give the IUPAC name for each of the following alcohols and phenols: (12.1)

c. <IMAGE>

Give the IUPAC name for each of the following alcohols and phenols: (12.1)

b. <IMAGE>

Give the IUPAC name for each of the following alcohols and phenols: (12.1)

c. <IMAGE>

Are each of the following soluble, slightly soluble, or insoluble in water? Explain.

a. CH₃—CH₂—CH₂—OH