In the Chemistry and the Environment box on free radicals in this chapter, we discussed the importance of the hydroxyl radical in reacting with and eliminating many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon: OH(g) + CF2Cl2(g) → HOF(g) + CFCl2(g) Use bond energies to explain why this reaction is improbable. (The C–F bond energy is 552 kJ/mol.)
Carbon ring structures are common in organic chemistry. Draw a Lewis structure for each carbon ring structure, including any necessary resonance structures. a. C4H8 b. C4H4 c. C6H12 d. C6H6


Verified Solution

Key Concepts
Lewis Structures
Resonance Structures
Hydrocarbons
Write an appropriate Lewis structure for each compound. Make certain to distinguish between ionic and molecular compounds. b. ClF5
Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each, including the covalent structure for the ion in brackets. Write resonance structures if necessary. a. BaCO3
Amino acids are the building blocks of proteins. The simplest amino acid is glycine (H2NCH2COOH). Draw a Lewis structure for glycine. (Hint: The central atoms in the skeletal structure are nitrogen and the two carbon atoms. Each oxygen atom is bonded directly to the right-most carbon atom.)
Formic acid is responsible for the sting of ant bites. By mass, formic acid is 26.10% C, 4.38% H, and 69.52% O. The molar mass of formic acid is 46.02 g/mol. Determine the molecular formula of formic acid and draw its Lewis structure.
Diazomethane is a highly poisonous, explosive compound because it readily evolves N2. Diazomethane has the following composition by mass: 28.57% C; 4.80% H; and 66.64% N. The molar mass of diazomethane is 42.04 g/mol. Find the molecular formula of diazomethane, draw its Lewis structure, and assign formal charges to each atom. Why is diazomethane not very stable? Explain.