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Ch.7 - Thermochemistry
Chapter 7, Problem 68

Charcoal is primarily carbon. Determine the mass of CO2 produced by burning enough carbon (in the form of charcoal) to produce 5.00×102 kJ of heat. C(s) + O2(g) → CO2(g) ΔH°rxn = –393.5 kJ

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the amount of substances consumed and produced in a reaction, using mole ratios derived from the coefficients in the balanced equation. In this case, it will help us relate the heat produced to the amount of carbon burned.
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Stoichiometry Concept

Enthalpy Change (ΔH)

Enthalpy change (ΔH) is a measure of the heat content of a system at constant pressure. In this reaction, the negative value of ΔH indicates that the reaction is exothermic, meaning it releases heat. Understanding ΔH is crucial for calculating how much carbon is needed to produce a specific amount of heat, as it directly relates the heat released to the moles of carbon consumed.
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Combustion Reaction

A combustion reaction is a chemical reaction that typically involves a fuel (like carbon) reacting with oxygen to produce heat and light, along with products such as carbon dioxide and water. In this scenario, the combustion of carbon produces CO2, and knowing the stoichiometry of the reaction allows us to calculate the mass of CO2 produced from the heat generated by burning charcoal.
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Related Practice
Textbook Question

Nitromethane (CH3NO2) burns in air to produce significant amounts of heat. 2 CH3NO2(l ) + 32 O2( g)¡2 CO2( g) + 3 H2O(l ) + N2( g) ΔH °rxn = -1418 kJ How much heat is produced by the complete reaction of 10.47 kg of nitromethane?

Textbook Question

Titanium reacts with iodine to form titanium(III) iodide, emitting heat. 2 Ti(s) + 3 I2( g)¡2 TiI3(s) ΔH °rxn = -839 kJ Determine the mass of titanium that react if 2.38 * 103 kJ of heat is emitted by the reaction.

Textbook Question

The propane fuel (C3H8) used in gas barbeques burns according to the thermochemical equation: C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g) ΔH°rxn = –2044 kJ If a pork roast must absorb 1.6×103 kJ to fully cook, and if only 10% of the heat produced by the barbeque is actually absorbed by the roast, what mass of CO2 is emitted into the atmosphere during the grilling of the pork roast?

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Textbook Question

A silver block, initially at 58.5 °C, is submerged into 100.0 g of water at 24.8 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 26.2 °C. What is the mass of the silver block?

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Textbook Question

A 32.5-g iron rod, initially at 22.7 °C, is submerged into an unknown mass of water at 63.2 °C, in an insulated container. The final temperature of the mixture upon reaching thermal equilibrium is 59.5 °C. What is the mass of the water?

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Textbook Question

A 31.1-g wafer of pure gold, initially at 69.3 °C, is submerged into 64.2 g of water at 27.8 °C in an insulated container. What is the final temperature of both substances at thermal equilibrium?

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