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Ch.4 - Chemical Reactions and Chemical Quantities
Chapter 4, Problem 54

Elemental phosphorus reacts with chlorine gas according to the equation: P4(s) + 6 Cl2( g) → 4 PCl3(l) A reaction mixture initially contains 91.38 g P4 and 262.6 g Cl2. Once the reaction has occurred as completely as possible, what mass (in g) of the excess reactant remains?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the proportions of substances consumed and produced, which is essential for identifying limiting and excess reactants in a reaction.
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Limiting Reactant

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. Identifying the limiting reactant is crucial for calculating how much of the excess reactant remains after the reaction has occurred.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is used to convert between the mass of a substance and the number of moles, which is necessary for stoichiometric calculations in chemical reactions.
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Related Practice
Textbook Question

For the reaction shown, calculate the theoretical yield of product (in grams) for each initial amount of reactants. 2 Al(s) + 3 Cl2(g) → 2 AlCl3(s) c. 0.235 g Al, 1.15 g Cl2

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Textbook Question

For the reaction shown, calculate the theoretical yield of the product (in grams) for each initial amount of reactants. Ti(s) + 2 F2( g) → TiF4(s) c. 0.233 g Ti, 0.288 g F2

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Textbook Question

Iron(III) oxide reacts with carbon monoxide according to the equation: Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g) A reaction mixture initially contains 45.10 g Fe2O3 and 29.56 g CO. Once the reaction has occurred as completely as possible, what mass (in g) of the excess reactant remains?

Textbook Question

Magnesium oxide can be made by heating magnesium metal in the presence of oxygen. The balanced equation for the reaction is: 2 Mg(s) + O2(g) → 2 MgO(s) When 13.1 g of Mg reacts with 13.6 g O2, 12.4 g MgO is collected. Determine the limiting reactant, theoretical yield, and percent yield for the reaction.

Textbook Question

Urea (CH4N2O) is a common fertilizer that is synthesized by the reaction of ammonia (NH3) with carbon dioxide: 2 NH3(aq) + CO2(aq) → CH4N2O(aq) + H2O(l) In an industrial synthesis of urea, a chemist combines 149.4 kg of ammonia with 231.1 kg of carbon dioxide and obtains 172.3 kg of urea. Determine the limiting reactant, theoretical yield of urea, and percent yield for the reaction.

Textbook Question

Many computer chips are manufactured from silicon, which occurs in nature as SiO2. When SiO2 is heated to melting, it reacts with solid carbon to form liquid silicon and carbon monoxide gas. In an industrial preparation of silicon, 177.4 kg of SiO2 reacts with 100.1 kg of carbon to produce 71.2 kg of silicon. Determine the percent yield for the reaction.