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Ch.4 - Chemical Reactions and Chemical Quantities
Chapter 4, Problem 68

Many home barbeques are fueled with propane gas (C3H8). What mass of carbon dioxide (in kg) is produced upon the complete combustion of 37.8 L of propane (approximate contents of one 5-gallon tank)? Assume that the density of the liquid propane in the tank is 0.621 g/mL. (Hint: Begin by writing a balanced equation for the combustion reaction.)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Reaction

A combustion reaction is a chemical process in which a substance reacts with oxygen to produce heat and light. In the case of propane (C3H8), the balanced equation for its complete combustion is C3H8 + 5 O2 → 3 CO2 + 4 H2O. Understanding this reaction is crucial for determining the products formed and their quantities during the combustion of propane.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced equation. It allows us to determine the amount of carbon dioxide produced from a given volume of propane by using mole ratios derived from the balanced equation. This concept is essential for converting between different units, such as liters of gas to grams of product.
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Density and Volume Conversion

Density is defined as mass per unit volume and is crucial for converting the volume of a substance into mass. In this problem, the density of liquid propane (0.621 g/mL) is used to convert the volume of propane (37.8 L) into grams. This conversion is necessary to relate the mass of propane to the mass of carbon dioxide produced during combustion.
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Related Practice
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The combustion of gasoline produces carbon dioxide and water. Assume gasoline to be pure octane (C8H18) and calculate the mass (in kg) of carbon dioxide that is added to the atmosphere per 10.0 kg of octane burned. (Hint: Begin by writing a balanced equation for the combustion reaction.)

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The combustion of liquid ethanol (C2H5OH) produces carbon dioxide and water. After 4.62 mL of ethanol (density = 0.789 g/mL) is allowed to burn in the presence of 15.55 g of oxygen gas, 3.72 mL of water (density = 1.00 g/mL) is collected. Determine the percent yield for the reaction. (Hint: Write a balanced equation for the combustion of ethanol.)

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The reaction of NH3 and O2 forms NO and water. The NO can be used to convert P4 to P4O6, forming N2 in the process. The P4O6 can be treated with water to form H3PO3, which forms PH3 and H3PO4 when heated. Find the mass of PH3 that forms from the reaction of 1.00 g of NH3.

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