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Ch.22 - Organic Chemistry
Chapter 22, Problem 38

Write structural formulas for any 6 of the 18 structural isomers of octane.

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Identify the molecular formula of octane, which is C_8H_{18}.
Understand that structural isomers have the same molecular formula but different connectivity of atoms.
Start with the straight-chain structure of octane, which is a linear chain of 8 carbon atoms.
Create a branched isomer by moving one carbon from the end of the chain to a position on the chain, such as 2-methylheptane.
Continue creating more branched isomers by varying the positions of the branches, such as 3-methylheptane, 2,2-dimethylhexane, 2,3-dimethylhexane, and 2,4-dimethylhexane.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Structural Isomers

Structural isomers are compounds that have the same molecular formula but differ in the arrangement of atoms. This variation can lead to different physical and chemical properties. For octane (C8H18), there are 18 structural isomers, which can be categorized into straight-chain and branched forms, showcasing the diversity of molecular structures possible with the same number of carbon and hydrogen atoms.
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Octane and Its Isomers

Octane is an alkane with eight carbon atoms, commonly represented by the formula C8H18. Its structural isomers include various arrangements of carbon atoms, such as straight chains and branched chains. Understanding the specific structural formulas of these isomers is crucial for applications in fields like organic chemistry and fuel science, where octane ratings are significant for gasoline performance.
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Drawing Structural Formulas

Drawing structural formulas involves representing the arrangement of atoms within a molecule, including bonds between them. For octane isomers, this means accurately depicting the carbon skeleton and the hydrogen atoms attached to each carbon. Familiarity with conventions such as line-angle formulas and the ability to visualize three-dimensional structures are essential skills for chemists when illustrating these isomers.
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Structural Formula