Chapter 19, Problem 35b
Without doing any calculations, determine the sign of ΔSsys for each chemical reaction. b. CH2=CH2( g) + H2( g) → CH3CH3( g)
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Calculate the change in entropy that occurs in the system when 1.50 mol of isopropyl alcohol (C3H8O) melts at its melting point (-89.5 °C). See Table 12.9 for heats of fusion.
Calculate the change in entropy that occurs in the system when 1.50 mol of diethyl ether (C4H10O) condenses from a gas to a liquid at its normal boiling point (34.6 °C). See Table 12.7 for heats of vaporization.
Without doing any calculations, determine the sign of ΔSsys for each chemical reaction. a. 2 KClO3(s) → 2 KCl(s) + 3 O2( g)
Without doing any calculations, determine the signs of ΔSsys and ΔSsurr for each chemical reaction. In addition, predict under what temperatures (all temperatures, low temperatures, or high temperatures), if any, the reaction is spontaneous. c. C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g) ΔH°rxn = -2044 kJ
Calculate ΔS surr at the indicated temperature for each reaction. d. ΔHrxn ° = +114 kJ; 77 K
Given the values of ΔH°rxn, ΔS°rxn, and T, determine ΔSuniv and predict whether or not each reaction is spontaneous. (Assume that all reactants and products are in their standard states.) a. ΔH°rxn = +135 kJ; ΔS°rxn = -282 J/K; T = 298 K