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Ch.15 - Chemical Kinetics
Chapter 15, Problem 63a

The half-life for the radioactive decay of U-238 is 4.5 billion years and is independent of initial concentration. How long will it take for 20% of the U-238 atoms in a sample of U-238 to decay?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Half-life

Half-life is the time required for half of the radioactive nuclei in a sample to decay. It is a constant property of each radioactive isotope, meaning it does not change regardless of the amount of substance present. For U-238, the half-life is 4.5 billion years, indicating that after this period, half of the original amount will have transformed into a different element.
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Zero-Order Half-life

Radioactive Decay

Radioactive decay is a stochastic process by which unstable atomic nuclei lose energy by emitting radiation. This process results in the transformation of the original isotope into a different element or isotope. The decay occurs at a predictable rate characterized by the half-life, allowing for calculations of how much of a substance remains after a given time.
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Rate of Radioactive Decay

Exponential Decay

Exponential decay describes the process by which a quantity decreases at a rate proportional to its current value. In the context of radioactive decay, this means that the number of undecayed nuclei decreases exponentially over time. The relationship can be expressed mathematically, allowing for the determination of the remaining quantity of a substance after a specific duration, such as calculating the time required for a certain percentage of decay.
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