Chapter 14, Problem 45
A solution contains 35 g of NaCl per 100.0 g of water at 25°C. Is the solution unsaturated, saturated, or supersaturated? (Use Figure 14.11.)
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Silver nitrate has a lattice energy of -820 kJ/mol and a heat of solution of 22.6 kJ/mol. Calculate the heat of hydration for silver nitrate.
Use the data to calculate the heats of hydration of lithium chloride and sodium chloride. Which of the two cations, lithium or sodium, has stronger ion–dipole interactions with water? Why?
Potassium nitrate has a lattice energy of -163.8 kcal/mol and a heat of hydration of -155.5 kcal/mol. How much potassium nitrate has to dissolve in water to absorb 1.00⨉102 kJ of heat?
A KNO3 solution containing 35 g of KNO3 per 100.0 g of water is cooled from 40°C to 0°C. What happens during cooling? (Use Figure 14.11.)
A KNO3 solution containing 35 g of KNO3 per 100.0 g of water is cooled from 40 °C to 0 °C. What happens during cooling? (Use Figure 14.11.)
A KCl solution containing 38 g of KCl per 100.0 g of water is cooled from 60 °C to 0 °C. What happens during cooling? (Use Figure 14.11.)