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Ch.12 - Liquids, Solids & Intermolecular Forces
Chapter 12, Problem 41d

Determine the kinds of intermolecular forces that are present in each element or compound. d. CH3OH

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Intermolecular Forces

Intermolecular forces are the attractive forces between molecules that influence physical properties such as boiling and melting points. These forces include hydrogen bonding, dipole-dipole interactions, and London dispersion forces. Understanding these forces is crucial for predicting the behavior of substances in different states of matter.
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Hydrogen Bonding

Hydrogen bonding is a specific type of strong dipole-dipole interaction that occurs when hydrogen is covalently bonded to highly electronegative atoms like oxygen, nitrogen, or fluorine. In the case of CH₃OH (methanol), the presence of the hydroxyl (-OH) group allows for significant hydrogen bonding, which greatly affects its physical properties, such as its relatively high boiling point.
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Polarity

Polarity refers to the distribution of electrical charge over the atoms in a molecule. A polar molecule has a significant difference in electronegativity between its atoms, leading to a dipole moment. In CH₃OH, the oxygen atom is more electronegative than the carbon and hydrogen atoms, creating a polar molecule that can engage in hydrogen bonding and dipole-dipole interactions.
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