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Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory
Chapter 11, Problem 59

Which hybridization scheme allows the formation of at least one p bond? sp3, sp2, sp3d2

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hybridization

Hybridization is a concept in chemistry that describes the mixing of atomic orbitals to form new hybrid orbitals. These hybrid orbitals can explain the geometry of molecular bonding. The most common types of hybridization include sp, sp2, and sp3, which correspond to different arrangements of electron pairs around a central atom.
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Sigma and Pi Bonds

In chemical bonding, a sigma (σ) bond is formed by the head-on overlap of orbitals, while a pi (π) bond is formed by the side-to-side overlap of p orbitals. Sigma bonds are the first bonds formed between two atoms, and pi bonds can only form in conjunction with sigma bonds, contributing to the double or triple bond character in molecules.
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Types of Hybridization

Different hybridization schemes correspond to different types of bonding and molecular geometries. For example, sp3 hybridization involves one s and three p orbitals, leading to single bonds only. In contrast, sp2 hybridization involves one s and two p orbitals, allowing for the formation of one pi bond alongside a sigma bond, which is essential for double bonds.
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