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Ch.4 - Chemical Reactions and Chemical Quantities
Chapter 4, Problem 48

Magnesium oxide can be made by heating magnesium metal in the presence of oxygen. The balanced equation for the reaction is: 2 Mg(s) + O2(g) → 2 MgO(s) When 10.1 g of Mg reacts with 10.5 g O2, 11.9 g MgO is collected. Determine the limiting reactant, theoretical yield, and percent yield for the reaction.

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1. First, calculate the number of moles of Mg and O<sub>2</sub> using their respective molar masses. The molar mass of Mg is approximately 24.31 g/mol and the molar mass of O<sub>2</sub> is approximately 32.00 g/mol. Use the formula: number of moles = mass / molar mass.
2. Next, determine the limiting reactant. This is the reactant that will be completely consumed first in the reaction. According to the balanced chemical equation, the mole ratio of Mg to O<sub>2</sub> is 2:1. Compare the mole ratio of the reactants to the stoichiometric ratio to determine the limiting reactant.
3. Once the limiting reactant is determined, calculate the theoretical yield of MgO. The theoretical yield is the maximum amount of product that can be formed from the limiting reactant. Use the stoichiometric ratio from the balanced chemical equation to calculate the theoretical yield.
4. The actual yield is the amount of product that was actually formed in the reaction. In this case, the actual yield is given as 11.9 g of MgO.
5. Finally, calculate the percent yield using the formula: percent yield = (actual yield / theoretical yield) * 100%. This gives the efficiency of the reaction.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Limiting Reactant

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. To identify the limiting reactant, one must compare the mole ratios of the reactants based on the balanced chemical equation. The reactant that produces the lesser amount of product is the limiting reactant.
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Theoretical Yield

The theoretical yield is the maximum amount of product that can be produced from a given amount of reactants, as calculated from the balanced chemical equation. It assumes complete conversion of the limiting reactant into product without any losses. This value is essential for calculating the efficiency of a reaction and is typically expressed in grams or moles.
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Percent Yield

Percent yield is a measure of the efficiency of a chemical reaction, calculated by comparing the actual yield of a product obtained from the experiment to the theoretical yield. It is expressed as a percentage using the formula: (actual yield / theoretical yield) × 100. A high percent yield indicates a successful reaction, while a low percent yield may suggest incomplete reactions or losses during the process.
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Related Practice
Textbook Question

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