Chapter 4, Problem 61
Aspirin can be made in the laboratory by reacting acetic anhydride (C4H6O3) with salicylic acid (C7H6O3) to form aspirin (C9H8O4) and acetic acid (C2H4O2). The balanced equation is: C4H6O3 + C7H6O3 → C9H8O4 + C2H4O2 In a laboratory synthesis, a student begins with 3.00 mL of acetic anhydride (density = 1.08 g/mL) and 1.25 g of salicylic acid. Once the reaction is complete, the student collects 1.22 g of aspirin. Determine the limiting reactant. Determine the theoretical yield of aspirin. Determine the percent yield for the reaction.
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Write the balanced equation for the reaction of hydrogen gas with bromine gas.
The combustion of gasoline produces carbon dioxide and water. Assume gasoline to be pure octane (C8H18) and calculate the mass (in kg) of carbon dioxide that is added to the atmosphere per 1.0 kg of octane burned. (Hint: Begin by writing a balanced equation for the combustion reaction.)
Many home barbeques are fueled with propane gas (C3H8). What mass of carbon dioxide (in kg) is produced upon the complete combustion of 18.9 L of propane (approximate contents of one 5-gallon tank)? Assume that the density of the liquid propane in the tank is 0.621 g/mL. (Hint: Begin by writing a balanced equation for the combustion reaction.)
The combustion of liquid ethanol (C2H5OH) produces carbon dioxide and water. After 4.62 mL of ethanol (density = 0.789 g/mL) is allowed to burn in the presence of 15.55 g of oxygen gas, 3.72 mL of water (density = 1.00 g/mL) is collected. Determine the percent yield for the reaction. (Hint: Write a balanced equation for the combustion of ethanol.)
The reaction of NH3 and O2 forms NO and water. The NO can be used to convert P4 to P4O6, forming N2 in the process. The P4O6 can be treated with water to form H3PO3, which forms PH3 and H3PO4 when heated. Find the mass of PH3 that forms from the reaction of 1.00 g of NH3.
An important reaction that takes place in a blast furnace during the production of iron is the formation of iron metal and CO2 from Fe2O3 and CO. Determine the mass of Fe2O3 required to form 910 kg of iron. Determine the amount of CO2 that forms in this process.