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Ch.4 - Chemical Reactions and Chemical Quantities
Chapter 4, Problem 67

A liquid fuel mixture contains 30.35% hexane (C6H14), 15.85% heptane (C7H16), and the rest octane (C8H18). What maximum mass of carbon dioxide is produced by the complete combustion of 10.0 kg of this fuel mixture?

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1
Determine the percentage of octane (C_8H_18) in the mixture by subtracting the percentages of hexane and heptane from 100%.
Calculate the mass of each component (hexane, heptane, and octane) in the 10.0 kg fuel mixture using their respective percentages.
Write the balanced chemical equations for the complete combustion of hexane, heptane, and octane. For example, the combustion of hexane is: C_6H_14 + \frac{19}{2}O_2 \rightarrow 6CO_2 + 7H_2O.
Use stoichiometry to calculate the moles of CO_2 produced from the complete combustion of each component. Use the molar mass of each hydrocarbon to convert mass to moles, and then use the balanced equations to find moles of CO_2.
Convert the total moles of CO_2 produced from all components to mass using the molar mass of CO_2 (44.01 g/mol) to find the maximum mass of CO_2 produced.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Reactions

Combustion reactions involve the reaction of a fuel with oxygen to produce carbon dioxide and water. In the case of hydrocarbons like hexane, heptane, and octane, the general reaction can be represented as C_nH_m + O_2 → CO_2 + H_2O. Understanding the stoichiometry of these reactions is essential for calculating the products formed from a given amount of fuel.
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Stoichiometry

Stoichiometry is the quantitative relationship between reactants and products in a chemical reaction. It allows us to determine how much of each substance is involved in the reaction based on balanced chemical equations. For this question, stoichiometry will be used to calculate the amount of carbon dioxide produced from the combustion of the fuel mixture.
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Molar Mass and Mass Percentages

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole. In this question, the mass percentages of hexane, heptane, and octane in the fuel mixture are used to determine the total mass of each component in the 10.0 kg mixture. This information is crucial for calculating the total amount of carbon dioxide produced during combustion.
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Related Practice
Textbook Question

The combustion of liquid ethanol (C2H5OH) produces carbon dioxide and water. After 4.62 mL of ethanol (density = 0.789 g/mL) is allowed to burn in the presence of 15.55 g of oxygen gas, 3.72 mL of water (density = 1.00 g/mL) is collected. Determine the percent yield for the reaction. (Hint: Write a balanced equation for the combustion of ethanol.)

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Textbook Question

The reaction of NH3 and O2 forms NO and water. The NO can be used to convert P4 to P4O6, forming N2 in the process. The P4O6 can be treated with water to form H3PO3, which forms PH3 and H3PO4 when heated. Find the mass of PH3 that forms from the reaction of 1.00 g of NH3.

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Textbook Question

An important reaction that takes place in a blast furnace during the production of iron is the formation of iron metal and CO2 from Fe2O3 and CO. Determine the mass of Fe2O3 required to form 910 kg of iron. Determine the amount of CO2 that forms in this process.

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Textbook Question

Titanium occurs in the magnetic mineral ilmenite (FeTiO3), which is often found mixed with sand. The ilmenite can be separated from the sand with magnets. The titanium can then be extracted from the ilmenite by the following set of reactions: FeTiO3(s) + 3 Cl2(g) + 3 C(s) → 3 CO(g) + FeCl2(s) + TiCl4(g) TiCl4(g) + 2 Mg(s) → 2 MgCl2(l) + Ti(s) Suppose that an ilmenite–sand mixture contains 22.8% ilmenite by mass and that the first reaction is carried out with a 90.8% yield. If the second reaction is carried out with an 85.9% yield, what mass of titanium can be obtained from 1.00 kg of the ilmenite– sand mixture?

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