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Ch.3 - Molecules and Compounds
Chapter 3, Problem 119

Combustion analysis of a 13.42-g sample of equilin (which contains only carbon, hydrogen, and oxygen) produces 39.61 g CO2 and 9.01 g H2O. The molar mass of equilin is 268.34 g/mol. Find its molecular formula.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Analysis

Combustion analysis is a technique used to determine the elemental composition of organic compounds. In this process, a sample is burned in excess oxygen, producing carbon dioxide and water. The masses of these products are measured, allowing for the calculation of the amounts of carbon, hydrogen, and oxygen in the original sample.
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Empirical Formula

The empirical formula represents the simplest whole-number ratio of the elements in a compound. To find it, the moles of each element are calculated from the combustion products, and then the ratios are simplified. This formula is crucial for determining the molecular formula when combined with the molar mass of the compound.
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Molecular Formula

The molecular formula indicates the actual number of atoms of each element in a molecule of a compound. It can be derived from the empirical formula by multiplying it by a whole number, which is determined by dividing the compound's molar mass by the molar mass of the empirical formula. This provides insight into the compound's structure and properties.
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