Skip to main content
Ch.2 - Atoms & Elements
Chapter 2, Problem 38

Sulfur and fluorine form several different compounds including sulfur hexafluoride and sulfur tetrafluoride. Decomposition of a sample of sulfur hexafluoride produces 4.45 g of fluorine and 1.25 g of sulfur, while decomposition of a sample of sulfur tetrafluoride produces 4.43 g of fluorine and 1.87 g of sulfur. Calculate the mass of fluorine per gram of sulfur for each sample and show that these results are consistent with the law of multiple proportions.

Verified step by step guidance
1
Identify the compounds involved: sulfur hexafluoride (SF_6) and sulfur tetrafluoride (SF_4).
For sulfur hexafluoride, calculate the mass of fluorine per gram of sulfur by dividing the mass of fluorine (4.45 g) by the mass of sulfur (1.25 g).
For sulfur tetrafluoride, calculate the mass of fluorine per gram of sulfur by dividing the mass of fluorine (4.43 g) by the mass of sulfur (1.87 g).
Compare the ratios of fluorine to sulfur for both compounds to see if they are in a simple whole number ratio, as predicted by the law of multiple proportions.
Conclude that the results are consistent with the law of multiple proportions if the ratios are simple whole numbers, indicating that the elements combine in fixed ratios to form different compounds.

Verified Solution

Video duration:
8m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Law of Multiple Proportions

The Law of Multiple Proportions states that when two elements form more than one compound, the ratios of the masses of one element that combine with a fixed mass of the other element can be expressed as small whole numbers. This principle helps to illustrate how different compounds can be formed from the same elements in varying proportions, reinforcing the idea of distinct chemical identities.
Recommended video:
Guided course
03:32
Law of Multiple Proportions

Mass Ratio Calculation

To analyze the compounds formed by sulfur and fluorine, one must calculate the mass ratio of fluorine to sulfur for each compound. This involves dividing the mass of fluorine by the mass of sulfur for each sample, allowing for a comparison of how the proportions of these elements vary between different compounds.
Recommended video:
Guided course
02:14
Neutron-Proton Ratio

Stoichiometry

Stoichiometry is the area of chemistry that deals with the quantitative relationships between the reactants and products in a chemical reaction. Understanding stoichiometry is essential for calculating the amounts of substances involved in reactions, which is crucial for demonstrating the law of multiple proportions in the context of the given compounds.
Recommended video:
Guided course
01:16
Stoichiometry Concept
Related Practice
Textbook Question

Two different compounds containing osmium and oxygen have the following masses of oxygen per gram of osmium: 0.168 and 0.3369 g. Show that these amounts are consistent with the law of multiple proportions.

1321
views
4
rank
Textbook Question

Palladium forms three different compounds with sulfur. The mass of sulfur per gram of palladium in each compound is listed here. Show that these masses are consistent with the law of multiple proportions. Compound Grams S per Gram Pd A 0.603 B 0.301 C 0.151

908
views
1
comments
Textbook Question

Sulfur and oxygen form both sulfur dioxide and sulfur trioxide. When samples of these are decomposed, the sulfur dioxide produces 3.49 g oxygen and 3.50 g sulfur, while the sulfur trioxide produces 6.75 g oxygen and 4.50 g sulfur. Calculate the mass of oxygen per gram of sulfur for each sample and show that these results are consistent with the law of multiple proportions.

2207
views
Textbook Question

Which statements are consistent with Dalton's atomic theory as it was originally stated? Why? a. Sulfur and oxygen atoms have the same mass. b. All cobalt atoms are identical. c. Potassium and chlorine atoms combine in a 1:1 ratio to form potassium chloride. d. Lead atoms can be converted into gold.

1210
views
Textbook Question

Which statements are inconsistent with Dalton's atomic theory as it was originally stated? Why? a. All carbon atoms are identical. b. An oxygen atom combines with 1.5 hydrogen atoms to form a water molecule. c. Two oxygen atoms combine with a carbon atom to form a carbon dioxide molecule. d. The formation of a compound often involves the destruction of one or more atoms.

1719
views
Textbook Question

Which statements are consistent with Rutherford's nuclear theory as it was originally stated? Why? a. The volume of an atom is mostly empty space. b. The nucleus of an atom is small compared to the size of the atom. c. Neutral lithium atoms contain more neutrons than protons. d. Neutral lithium atoms contain more protons than electrons.

883
views