Calculate E°cell for each balanced redox reaction and determine if the reaction is spontaneous as written. b. MnO2(aq) + 4 H+(aq) + Zn(s) → Mn2+(aq) + 2H2O(l) + Zn2+(aq) c. Cl2(g) + 2 F–(aq) → F2(g) + 2 Cl–(aq)
Ch.20 - Electrochemistry
Chapter 20, Problem 38b
Balance each redox reaction occurring in acidic aqueous solution. b. Mg(s) + Cr3+(aq) → Mg2+(aq) + Cr(s)
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Redox Reactions
Redox reactions, or reduction-oxidation reactions, involve the transfer of electrons between two species. In these reactions, one species is oxidized (loses electrons) while another is reduced (gains electrons). Understanding the oxidation states of the elements involved is crucial for identifying which species undergo oxidation and reduction.
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Balancing Redox Reactions
Balancing redox reactions requires ensuring that both mass and charge are conserved. This often involves separating the reaction into half-reactions: one for oxidation and one for reduction. In acidic solutions, hydrogen ions (H+) and water (H2O) are typically added to balance the equation, along with electrons to balance the charges.
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Acidic Aqueous Solution
An acidic aqueous solution contains a higher concentration of hydrogen ions (H+) than hydroxide ions (OH-). This environment affects the behavior of the reactants and products in a redox reaction. When balancing reactions in such solutions, it is essential to account for the presence of H+ ions and water, which can influence the overall stoichiometry of the balanced equation.
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Related Practice
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