For each solution, calculate the initial and final pH after adding 0.010 mol of NaOH. a. 250.0 mL of pure water b. 250.0 mL of a buffer solution that is 0.195 M in HCHO2 and 0.275 M in KCHO2 c. 250.0 mL of a buffer solution that is 0.255 M in CH3CH2NH2 and 0.235 M in CH3CH2NH3Cl
Ch.18 - Aqueous Ionic Equilibrium
Chapter 18, Problem 53b
Determine whether or not the mixing of each pair of solutions results in a buffer. b. 50.0 mL of 0.10 M HCl; 35.0 mL of 0.150 M NaOH
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Identify the components of the solutions: HCl is a strong acid and NaOH is a strong base.
Calculate the moles of HCl: \( \text{moles of HCl} = 0.10 \, M \times 0.050 \, L \).
Calculate the moles of NaOH: \( \text{moles of NaOH} = 0.150 \, M \times 0.035 \, L \).
Determine the limiting reactant by comparing the moles of HCl and NaOH.
Assess if there is an excess of either component after the reaction. A buffer forms if there is a weak acid or weak base and its conjugate present in significant amounts.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Buffer Solutions
A buffer solution is a system that resists changes in pH upon the addition of small amounts of acid or base. It typically consists of a weak acid and its conjugate base or a weak base and its conjugate acid. Buffers are crucial in maintaining stable pH levels in various chemical and biological processes.
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Buffer Solutions
Strong Acids and Bases
Strong acids, like HCl, completely dissociate in water, releasing all their protons (H+), while strong bases, like NaOH, completely dissociate to produce hydroxide ions (OH-). The complete dissociation of these substances means they do not form a buffer solution when mixed, as they do not provide the weak acid/base pair necessary for buffering.
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Neutralization Reaction
A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In the given scenario, mixing HCl and NaOH will lead to a neutralization reaction, resulting in the formation of water and sodium chloride (NaCl). This reaction will not create a buffer, as it consumes both the acid and base completely.
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Related Practice
Textbook Question
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Textbook Question
A 100.0-mL buffer solution is 0.100 M in NH3 and 0.125 M in NH4Br. What mass of HCl can this buffer neutralize before the pH falls below 9.00?
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Textbook Question
Determine whether or not the mixing of each pair of solutions results in a buffer. a. 100.0 mL of 0.10 M NH3; 100.0 mL of 0.15 M NH4Cl
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Textbook Question
Determine whether or not the mixing of each pair of solutions results in a buffer. c. 50.0 mL of 0.15 M HF; 20.0 mL of 0.15 M NaOH
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Textbook Question
Determine whether or not the mixing of each pair of solutions results in a buffer. d. 175.0 mL of 0.10 M NH3; 150.0 mL of 0.12 M NaOH
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Textbook Question
Determine whether or not the mixing of each pair of solutions results in a buffer. e. 125.0 mL of 0.15 M NH3; 150.0 mL of 0.20 M NaOH
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