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Ch.18 - Aqueous Ionic Equilibrium
Chapter 18, Problem 35

A buffer contains significant amounts of acetic acid and sodium acetate. Write equations showing how this buffer neutralizes added acid and added base.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Buffer Solutions

Buffer solutions are mixtures that resist changes in pH when small amounts of acid or base are added. They typically consist of a weak acid and its conjugate base, or a weak base and its conjugate acid. In this case, acetic acid (a weak acid) and sodium acetate (its conjugate base) form a buffer that can maintain a stable pH.
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Neutralization Reactions

Neutralization reactions occur when an acid reacts with a base to form water and a salt. In the context of a buffer, when added acid (H⁺ ions) is introduced, it reacts with the conjugate base (acetate ions) to form more acetic acid, thereby minimizing pH changes. Conversely, when a base is added, it reacts with the weak acid to form water and the conjugate base.
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Equilibrium in Buffer Systems

Buffer systems operate based on the principle of chemical equilibrium, where the concentrations of the weak acid and its conjugate base adjust to counteract changes in pH. The equilibrium can shift in response to added acids or bases, allowing the buffer to maintain a relatively constant pH. This dynamic balance is crucial for the buffer's effectiveness in biological and chemical systems.
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